please help with these reactions 12. What is the product? Pay attention to stereochemistry chlorin Cl2...
12. What is the product? Pay attention to stereochemistry Cl2 H20 13. Predict the product of these reactions: 1)BH, THF 2) H2O2-OH H.SO H20
(30 pt) Draw the structures of the MAJOR products for the following reactions. Be sure to clearly show the REGIO- and STEREOCHEMISTRY of each product. H2SO4 X - H2O BH3 H2O2 THF H20, OH Br2 CH2OH excess HBO d) CH3-C=C-CH3 1 eq Cl2 e) CH3 -C=C-CH3 CH2Cl2 Na CH3CO2H 9) CH.-C=C-H, under CH3COH f) CH3-CEC-CH3 liquid NH3 -78 °C H202 g) CH3CH2-CEC-H R2BH THE H2O, OH NaNH2 CH3CH2Br H2SO4 h) CH3CH2-CEC-H my Chcn=c20-n, Nanets, Cheka na H2O HgSO4 heat 1...
3. Predict the majoe product(s) for the following reactions. Show the stereochemistry of the product(s) when applicable. HCI (1) Hg(OAc)2 (2) NaBH4 (1) BH3 THF (2) H202. OH Br, Br2. H20 Pt (I) CH3CO3H (2) H,O+ (2) DMS HBr ROOR
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
2. Predict the product(s) to the following reactions, pay attention to stereochemistry: (14pt) 1. NaNH2 3. Hº 1. Oa, -78C 2. H20 H, Pd Baso 1. NaNH2 2. Br. 2 H2 HgSO4 H2SO4 1. Sia BH 2. H2Oz/NaOH
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
suggest the major product(s) for the following reactions. specify the stereochemistry clearly and write "racemic" for a racemic product. Br КОН heat BH3, THF NaOH, H2O2 NaN3 DMSO Br HCI SOH HBr
(4 pts 2 pts EC) Predict the products for the following reactions. Pay attention to stereochemistry 2. where appropriate HO SOCI2 а. dioxane 1) TsC pyridine Он b. 2) LIAIH4 1) TsCl pyridine но° C. 2) Nal OH РСС d. CH2CI2 он NaOCI но, acetic acid он NaOCI Он ТЕMPO
4. Give the major product for each of the following reactions. Pay attention to the regiochemistry and stereochemistry where appropriate. (6 pts) НС CH2C2 CH3 Н- но b) Н- Br (You might want to use a model to figure this one out.) CH-CHз 1) Hg(CH3CO2)2, H20 c 2) NaBH4 Br2 CH30H 1) ВНз, THF 2) H2О2, НО- CH-CHз CH3 СHCI3, HO- f) Н Н Ph
1. Draw all major products (or product) for the following reactions. Pay attention to stereochemistry where appropriate. (5 pts) a. 2. Br2, FeBr3