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10) Which of the following reactions will not yield will not yield a ketone product? A)...
6. Name the following compound. Br ☺i 7. Provide the products for the following reactions. A)...
6. Name the following compound. Br ☺i 7. Provide the products for the following reactions. A) 1. Sia BH/ THE 2. H2O/OH CECH B) -CEDI 1. CH3 CH MgBr 2. H30+ C) 1 2 CHỊCH Li 2. H30+ OH D) AlCl3 H3c1 E) OH PCC
or esterfication for D Which method would give this ketone? CH,CHE 1. PhMgBr 2. H307 1....
or
esterfication for D
Which method would give this ketone? CH,CHE 1. PhMgBr 2. H307 1. CH3CH MgBr 2. Hz0+ 1. CH2CHCN 2. PHCN CH3CH,COCI, AICI: TOLONIA O2 and 3 only 1 and 3 only 1. NaCN 2. H30, Heat CONH2 COH со,Н NH2 Question 14 (1 point) Which structure is consistent with the following proton NMR data: 1.2 (3H, triplet, J = 8Hz), 3.7 (2H, quartet, J = 8Hz), 4.1 (2H, singlet), 11.1 (1H, singlet) CH2CH3 och Por o...
2) Starting from benzene, use the reagents below to synthesize acetophenone (methyl phenyl ketone). There are...
2) Starting from benzene, use the reagents below to synthesize acetophenone (methyl phenyl ketone). There are two possible ways to accomplish this; give both. You may draw the intermediates in any format. Starting from benzene you have to figure out how to make the appropriate Grignard reagent 2 in two steps... 3) A, B, C, D, E? Route A: Choose one СН3 Na2Cr207 H.S04. H2O H30® workup Now convert Intermediate 2 to acetophenone... 2- acetophenone Route B: Choose one 3)...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
1. What will be the products (A-D) in the following aldehyde and ketone reactions ? Hoon...
1. What will be the products (A-D) in the following aldehyde and ketone reactions ? Hoon 1) SOCI 2) (CH3)2NH A FO сндон, H30* OH B CH H₃C. OH H3C Pyridine H3C CH, с مل CH3NH2, A D 2. Provide IUPAC names for the following compounds (E-G). Name: нас. сн, сн. E Name: H3C CH3 CH3 F Name: HO OH CH3 G 3. Provide a mechanism for the following reactions a) OCH3 CH3NH2, 4 NHCH3 b) FO 1) SOCI 2)...
Select the correct product from the following reactions 1. (Sia)2BH 5. 2.4,03, NaOH M M M...
Select the correct product from the following reactions 1. (Sia)2BH 5. 2.4,03, NaOH M M M H - Nat 6. Product of 5 2. H30 OH Na, NHS 8. Product of 7 mCPBA - ZBr + Bre – 10 . + 2. Mess " - ಯ - ಜಿ ಯೆ " ಯ . - ಗೆ a - 2, - : " ಯ : – ರ ' ರ " “O - DARS, - - * ಡ - - - " . *...
Which of the following reactions would not normally yield an alcohol? A. Oxymercuration/ de mercuraction of...
Which of the following reactions would not normally yield an alcohol? A. Oxymercuration/ de mercuraction of alkenes B. Hydroboration of alkene C. Reaction of a carboxylic acid with NaBH4 D. Reaction of ketone with a Grignard reagent Which set of reagents is the best to perform the following transformation? OH step(s) A. PCC; CH2MgBr, POCIz/pyridine B. tosyl chloride; CH3MgBr C. PBrz; Mg(0); CH31 D. CrOz/H3O+; NaBH4, CH MgBr 1) excess LiAIHA 2) Н,0* І, Но но- Но он но- он...
2. For 2a - 2j. predict the product or products for the following reactions. If no...
2. For 2a - 2j. predict the product or products for the following reactions. If no reaction occurs for the given conditions write no reaction and explain why there is no reaction. You must indicate the correct stereochemistry where needed in order to get full credit. (3 points each) NOTE: any carbon atom with a start next to it (C) indicates that this Carbon atom can be in either the R-or S- absolute configuration. 2a. 1. 2 mol O2 2....
59. Provide the major organic product in the reaction shown below. 1. NH4 2. KOH, heat...
59. Provide the major organic product in the reaction shown below. 1. NH4 2. KOH, heat 0 3. H20 60. O= 1. NH2NH2 H₃C 0 CH2 CH3 2. "OH, heat ii. What is the reactant W in the synthesis given below? a) Cyclopentanone b) Cyclopentene c) Cyclopentanol d) Bromocyclopentane e) Triphenylphosphine oxide What is the final product of this synthetic sequence? | Br2 Mg 1. C,H,CHO H Cr,04 Benzene FeCl, ether 2. H,0 acetone d) e) CHECCHS p-BrC.H.CH.C.HSCH:CHCOOH CA HECH,...
22. What is the major organic product obtained from the following reaction? ho A) 2 B)4...
22. What is the major organic product obtained from the following reaction? ho A) 2 B)4 C)3 D) 1 23. What is the correct name for the molecule below: A) 2,6-dimethyl-3-oxonon-2-ene B) B) 2,6-dimethylnona-8-oxone C) C) 4,8-dimethylnon-7-en-2-one D) 4,8-dimethyl-2-oxonon-7-ene 24. Which of the following describes a synthesis of an aldehyde? A) hydrogenation of an acid chloride using Pd/BaSO4/S as a poisoned catalyst B) reaction of a primary alcohol with Na2Cr207 C) reaction of a ketone with ozone D) treatment of...
6. Name the following compound. Br ☺i 7. Provide the products for the following reactions. A) 1. Sia BH/ THE 2. H2O/OH CECH B) -CEDI 1. CH3 CH MgBr 2. H30+ C) 1 2 CHỊCH Li 2. H30+ OH D) AlCl3 H3c1 E) OH PCC
or
esterfication for D
Which method would give this ketone? CH,CHE 1. PhMgBr 2. H307 1. CH3CH MgBr 2. Hz0+ 1. CH2CHCN 2. PHCN CH3CH,COCI, AICI: TOLONIA O2 and 3 only 1 and 3 only 1. NaCN 2. H30, Heat CONH2 COH со,Н NH2 Question 14 (1 point) Which structure is consistent with the following proton NMR data: 1.2 (3H, triplet, J = 8Hz), 3.7 (2H, quartet, J = 8Hz), 4.1 (2H, singlet), 11.1 (1H, singlet) CH2CH3 och Por o...
2) Starting from benzene, use the reagents below to synthesize acetophenone (methyl phenyl ketone). There are two possible ways to accomplish this; give both. You may draw the intermediates in any format. Starting from benzene you have to figure out how to make the appropriate Grignard reagent 2 in two steps... 3) A, B, C, D, E? Route A: Choose one СН3 Na2Cr207 H.S04. H2O H30® workup Now convert Intermediate 2 to acetophenone... 2- acetophenone Route B: Choose one 3)...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
1. What will be the products (A-D) in the following aldehyde and ketone reactions ? Hoon 1) SOCI 2) (CH3)2NH A FO сндон, H30* OH B CH H₃C. OH H3C Pyridine H3C CH, с مل CH3NH2, A D 2. Provide IUPAC names for the following compounds (E-G). Name: нас. сн, сн. E Name: H3C CH3 CH3 F Name: HO OH CH3 G 3. Provide a mechanism for the following reactions a) OCH3 CH3NH2, 4 NHCH3 b) FO 1) SOCI 2)...
Select the correct product from the following reactions 1. (Sia)2BH 5. 2.4,03, NaOH M M M H - Nat 6. Product of 5 2. H30 OH Na, NHS 8. Product of 7 mCPBA - ZBr + Bre – 10 . + 2. Mess " - ಯ - ಜಿ ಯೆ " ಯ . - ಗೆ a - 2, - : " ಯ : – ರ ' ರ " “O - DARS, - - * ಡ - - - " . *...
Which of the following reactions would not normally yield an alcohol? A. Oxymercuration/ de mercuraction of alkenes B. Hydroboration of alkene C. Reaction of a carboxylic acid with NaBH4 D. Reaction of ketone with a Grignard reagent Which set of reagents is the best to perform the following transformation? OH step(s) A. PCC; CH2MgBr, POCIz/pyridine B. tosyl chloride; CH3MgBr C. PBrz; Mg(0); CH31 D. CrOz/H3O+; NaBH4, CH MgBr 1) excess LiAIHA 2) Н,0* І, Но но- Но он но- он...
2. For 2a - 2j. predict the product or products for the following reactions. If no reaction occurs for the given conditions write no reaction and explain why there is no reaction. You must indicate the correct stereochemistry where needed in order to get full credit. (3 points each) NOTE: any carbon atom with a start next to it (C) indicates that this Carbon atom can be in either the R-or S- absolute configuration. 2a. 1. 2 mol O2 2....
59. Provide the major organic product in the reaction shown below. 1. NH4 2. KOH, heat 0 3. H20 60. O= 1. NH2NH2 H₃C 0 CH2 CH3 2. "OH, heat ii. What is the reactant W in the synthesis given below? a) Cyclopentanone b) Cyclopentene c) Cyclopentanol d) Bromocyclopentane e) Triphenylphosphine oxide What is the final product of this synthetic sequence? | Br2 Mg 1. C,H,CHO H Cr,04 Benzene FeCl, ether 2. H,0 acetone d) e) CHECCHS p-BrC.H.CH.C.HSCH:CHCOOH CA HECH,...
22. What is the major organic product obtained from the following reaction? ho A) 2 B)4 C)3 D) 1 23. What is the correct name for the molecule below: A) 2,6-dimethyl-3-oxonon-2-ene B) B) 2,6-dimethylnona-8-oxone C) C) 4,8-dimethylnon-7-en-2-one D) 4,8-dimethyl-2-oxonon-7-ene 24. Which of the following describes a synthesis of an aldehyde? A) hydrogenation of an acid chloride using Pd/BaSO4/S as a poisoned catalyst B) reaction of a primary alcohol with Na2Cr207 C) reaction of a ketone with ozone D) treatment of...
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