The equilibrium constant for the equation Ag+ (aq) + 2NH, (aq) =[Ag(NH),]+(aq) is Kf = 2.5...
The equilibrium constant for the equation HNO3(aq) + H2O(l) = H, 0+ (aq) + NO2 (aq) is Kg = 5.6 x 10-4 M at 25.0 °C. Calculate the value of AGixn at 25.0 °C for nitrous acid when [NO2] = [H3O+] = [HNO2] = 1.00 M. AGixn = kJ/mol Will the acid spontaneously dissociate under these conditions? O no O yes Calculate the value of AGrxn for nitrous acid when [NO, ] = [H,O+] = 7.13 x 10- M and...
A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reaction ATP(aq) + H, O(1) — ADP(aq) + HPO2 (aq) for which AGixn = -30.5 kJ/mol at 37.0 °C and pH 7.0. Calculate the value of AGrxn in a biological cell in which [ATP] = 5.0 mM, [ADP] = 0.50 mM, and [HPO2-) = 5.0 mM. AGrx...
The equilibrium constant for the reaction Agl(s) — Ag+ (aq) +1 (aq) is the solubility product constant, Ksp = 8.3 x 10-17 at 25°C. Calculate AG for the reaction when [Ag+]=1.5 x 10-3 M and [Br] =1.5 x 10-2 M. Is the reaction spontaneous or nonspontaneous at these concentrations? AG = 98 kJ/mol, spontaneous AG = 92 kJ/mol, nonspontaneous AG = -65 kJ/mol, spontaneous AG = 65 kJ/mol, nonspontaneous AG = -92 kJ/mol, spontaneous
Calculate the standard change in Gibbs free energy, AGixn , for the given reaction at 25.0 °C. Consult the table of thermodynamic properties for standard Gibbs free energy of formation values. NH,CI() = NH(aq) + Cl(aq) AGxn = -7.7 kJ/mol Determine the concentration of NH(aq) if the change in Gibbs free energy, AGrxn , for the reaction is –9.53 kJ/mol. [NH] = 0.72 Consider a general reaction enzyme A(aq) = B(aq) The AG® of the reaction is -4.880 kJ mol-....
A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reaction..... Thank you!!! A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reaction ATP(aq) + H2O(1) ADP(aq) + HPO2 (aq) in a biological...
A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reaction ATP(aq) + H2O(l) —— ADP(aq) + HPO2 (aq) for which AGix = -30.5 kJ/mol at 37.0 °C and pH 7.0. Calculate the value of AGrxn in a biological cell in which [ATP] = 5.0 mm, (ADP) = 0.20 mM, and [HPO2-) = 5.0 mM. AGxn= kJ/mol...
1. (3pts.) Complete and balance the nuclear equation in+U - Br+3n+ 2. The equilibrium constant for the dissociation of As.CO, (s) + 2 Ag+CO, isk=8.1 10-at 25°C. a) Calculate AG for the reaction when Agtl -1.0 x 102 M and CO, 9-10 x 10 M. (4pts) Ans: b) (pt) is the reaction spontaneous or onspontaneous at these concentrations? Ans: 3. (4pts) Nitrosyl chloride (NOCI) decomposes at elevated temperatures according to the equation below; INOCHE 2NO(g) + Calculate K, for this...
The equilibrium constant for the following reaction Ag+(aq) + 2NH3(aq) Ag(NH3)2+(aq) is K = 1.7 × 107 at 25°C. What is ΔG° at this temperature? Question 10 options: a) –1.5 kJ b) –23 kJ c) –41 kJ d) –3.5 kJ e) –18 kJ
Determine the standard entropy change of the universe at 25°C for the reaction NHİ (aq) + Cl-(aq) NH, Cl (s) given the following information. Is the reaction spontaneous under standard conditions? Substance Δ AHP(kJ/mol) S° (J/mol K) NH,Cl(s) NH (aq) Cl (aq) -314.4 -132.5 -167.2 94.6 113.4 56.5 +124.6 J/K, yes +26.0 J/K, yes d. a. -26.0 J/K, no b. +49.3 J/K, yes c. -75.3 J/K, no e.
In Class Exercise - The Gibbs Free Energy Change, AG 1) Determining the Standard Gibbs Free Energy Change (AGⓇ) for a Chemical Reaction 2) Using AGº to Determine Spontaneity Name: Date: Lab section: Show your work when there are calculations, write units, and use correct significant figures. Consider the following reaction (balanced as written) and thermodynamic data from tables in your book: CO(NH2)2(aq) + H2O(1) ► CO2(g) + 2NH3(g) Substance CO(NH3)2(aq) H00 AH(kJ/mol) 1-391.2 -285.9 -3935 -46.19 S'J/mol K) 173.8...