(b) Explain the following pKa values by drawing out resonance structures of the conjugate base for...
draw resonance structures for the conjugate base of 2,6dichloroibdophenol and use them to explain the differences in the pka values a value of 5.9 and is 10.000 times more 2,6-dichloroindophenol (see in Part III) has a pka value of 5.9 and is 10000 acidic than phenol (pKa =10). Draw resonance structures for the conjugate base of 26 dichloroindophenol and use them to explain the differences in the pKa values.
Explain why the different positions have different pKa values, using resonance structures. The pka of phenol (C6H5OH) is 10.0. When a nitro group (NO) is attached to the ring, the pka decreases. Explain why the different positions have different pka values, using resonance structures. OH OH OH - ၄ NO, NO₂ 10. 0 pK, = 7 .23 8.35 7.1
1. 2,6-dichloroindophenol has a pKa value of 5.9 and is 10,000 times more acidic than phenol (pKa = 10). Draw resonance structures for the conjugate base of 2,6-dichloroindophenol and use them to explain the differences in pKa values.
Please Explain: 7) a. Why does an acid and its conjugate base have the same pKa and Ka values? b. Why does a base and its conjugate acid have the same pKa and Ka values? Thank You! <3
Organic Chemistry 4. Below are two molecules, B and C. Explain the differences in pKa of the two molecules by drawing the conjugate base of molecule C and a resonance structure that would not be found in molecule B. Hint: Draw out the NO2 group. conjugate base of molecule C pKa- 29.5 molecule B NO2 pka= 8.6 molecule C 5. Below is the molecule Abilify, which is a top selling drug that is used to treat schizophrenia, bipolar disorder and...
6. Usina resonance structures, explain why acetaldenyde has a pka of 17, while acetone of 19. 7. Using resonance structures, explain why methyl acetate (pka 25) is less acidic than acetone (pka 19). 8. Rank the following in order from least to most acidic. Explain your ranking, using resonance structures with your explanation. & la
3) Draw resonance diagrams to explain why phenol has a pka pf 10 whereas aliphatic alcohols like ethanol have a pka of 16. 4) Why are aldehydes generally more reactive towards nucleophilic attack than ketones? 5) Suggest possible steps involved in the synthesis of the following compound starting propene. Note for each step involved your desired product must be a major product. Also note the two arrows indicate an unknown number of steps are involved.
(c) Phenol (C6H5OH) and 2,4,6-trichlorophenol (C6H2C13OH) are both weak acids with pKa values of 9.89 and 6.21, respectively, at 298.15 K. (i) Write down the dissociation reaction and corresponding expression for the equilibrium constant for 2,4,6-trichlorophenol. What is the conjugate base of this acid? (3 marks)
3. a) For the following reaction, label the acid and the base. Then draw the structures of the conjugate acid and base. н ............ conjugate acid conjugate base b) Clearly show the movement of electrons (arrow-pushing mechanism) for the reaction. c) Write the pka values under the acid and conjugate acid. Draw your equilibrium arrow to favor the direction toward the weaker acid (think about what the pka value tells you about acidity).
2. Rank the following compounds in order of increasing pKa values (for part (a) - 1: lowest pKa, 3: highest pKa and for part (b) -1: lowest pKa, 4: highest pKa). Draw the structures of the conjugate base to rationalize your answers. OH OH