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O GASES Calculating mole fraction in a ges mbxture Christo A 10.00 L tank at 10.4 °C is filled with 3.99 g of sulfur hexafluo
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Answer:-

Given:-

volume of tank (V) = 10.00 L

temperature (T) = 10.4 0C

wt. or mass of sulfur hexafluoride gas (SF6) = 3.99 g

wt. or mass of chlorine pentafluoride gas (ClF5) = 14.6 g

mole fraction of sulfur hexafluoride gas (\chiSF6) = ?

mole fraction of chlorine pentafluoride gas (\chiClF5) = ?

As we know that

molar mass of sulfur hexafluoride gas (SF6) = molar mass of S + 6 \times molar mass of F

molar mass of sulfur hexafluoride gas (SF6) = 32 + 6 \times 19

molar mass of sulfur hexafluoride gas (SF6) = 32 + 114

molar mass of sulfur hexafluoride gas (SF6) = 146 g / mol

similarly

molar mass of chlorine pentafluoride gas (ClF5) = molar mass of Cl + 5 \times molar mass of F

molar mass of chlorine pentafluoride gas (ClF5) = 35.5 + 5 \times 19

molar mass of chlorine pentafluoride gas (ClF5) = 35.5 + 95

molar mass of chlorine pentafluoride gas (ClF5) = 130.5 g / mol

Also we know that

No. of moles compound (n) = wt.or mass of compound (g) / molar mass of compound ( g / mol)

therefore

No. of moles of sulfur hexafluoride gas (nSF6) = wt.or mass of sulfur hexafluoride gas (SF6) (g) / molar mass of sulfur hexafluoride gas (SF6) ( g / mol)

No. of moles of sulfur hexafluoride gas (nSF6) = 3.99 g / 146 g / mol

No. of moles of sulfur hexafluoride gas (nSF6) = 0.0273 mol

similarly

No. of moles of chlorine pentafluoride gas (nClF5) = wt.or mass of chlorine pentafluoride gas (ClF5) (g) / molar mass of chlorine pentafluoride gas (ClF5) ( g / mol)

No. of moles of chlorine pentafluoride gas (nClF5) = 14.6 g / 130.5 g / mol

No. of moles of chlorine pentafluoride gas (nClF5) = 0.1119 mol

So

Total no. of moles present in 10.00 L tank (ntotal) = No. of moles of sulfur hexafluoride gas (nSF6) + No. of moles of chlorine pentafluoride gas (nClF5)

Total no. of moles present in 10.00 L tank (ntotal) = 0.0273 mol + 0.1119 mol

Total no. of moles present in 10.00 L tank (ntotal) = 0.1392‬ mol

therefore

According to the formula

mole fraction of sulfur hexafluoride gas (\chiSF6) = No. of moles of sulfur hexafluoride gas (nSF6) / Total no. of moles present in 10.00 L tank (ntotal)

mole fraction of sulfur hexafluoride gas (\chiSF6) = 0.0273 mol / 0.1392‬ mol

mole fraction of sulfur hexafluoride gas (\chiSF6) = 0.1961

mole fraction of sulfur hexafluoride gas (\chiSF6) = 0.196 ( 3 significant digits) i.e the answer

similarly

mole fraction of chlorine pentafluoride gas (\chiClF5) = No. of moles of chlorine pentafluoride gas (nClF5) / Total no. of moles present in 10.00 L tank (ntotal)

mole fraction of chlorine pentafluoride gas (\chiClF5) = 0.1119 mol / 0.1392‬ mol

mole fraction of chlorine pentafluoride gas (\chiClF5) = 0.8038

mole fraction of chlorine pentafluoride gas (\chiClF5) = 0.804 ( 3 significant digits) i.e the answer

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