Answer:-
Given:-
volume of tank (V) = 10.00 L
temperature (T) = 10.4 0C
wt. or mass of sulfur hexafluoride gas (SF6) = 3.99 g
wt. or mass of chlorine pentafluoride gas (ClF5) = 14.6 g
mole fraction of sulfur hexafluoride gas (SF6)
= ?
mole fraction of chlorine pentafluoride gas (ClF5)
= ?
As we know that
molar mass of sulfur hexafluoride gas (SF6) = molar
mass of S + 6
molar mass of F
molar mass of sulfur hexafluoride gas (SF6) = 32 + 6
19
molar mass of sulfur hexafluoride gas (SF6) = 32 + 114
molar mass of sulfur hexafluoride gas (SF6) = 146 g / mol
similarly
molar mass of chlorine pentafluoride gas (ClF5) =
molar mass of Cl + 5
molar mass of F
molar mass of chlorine pentafluoride gas (ClF5) =
35.5 + 5
19
molar mass of chlorine pentafluoride gas (ClF5) = 35.5 + 95
molar mass of chlorine pentafluoride gas (ClF5) = 130.5 g / mol
Also we know that
No. of moles compound (n) = wt.or mass of compound (g) / molar mass of compound ( g / mol)
therefore
No. of moles of sulfur hexafluoride gas (nSF6) = wt.or mass of sulfur hexafluoride gas (SF6) (g) / molar mass of sulfur hexafluoride gas (SF6) ( g / mol)
No. of moles of sulfur hexafluoride gas (nSF6) = 3.99 g / 146 g / mol
No. of moles of sulfur hexafluoride gas (nSF6) = 0.0273 mol
similarly
No. of moles of chlorine pentafluoride gas (nClF5) = wt.or mass of chlorine pentafluoride gas (ClF5) (g) / molar mass of chlorine pentafluoride gas (ClF5) ( g / mol)
No. of moles of chlorine pentafluoride gas (nClF5) = 14.6 g / 130.5 g / mol
No. of moles of chlorine pentafluoride gas (nClF5) = 0.1119 mol
So
Total no. of moles present in 10.00 L tank (ntotal) = No. of moles of sulfur hexafluoride gas (nSF6) + No. of moles of chlorine pentafluoride gas (nClF5)
Total no. of moles present in 10.00 L tank (ntotal) = 0.0273 mol + 0.1119 mol
Total no. of moles present in 10.00 L tank (ntotal) = 0.1392 mol
therefore
According to the formula
mole fraction of sulfur hexafluoride gas (SF6)
= No. of moles of sulfur hexafluoride gas (nSF6) / Total
no. of moles present in 10.00 L tank (ntotal)
mole fraction of sulfur hexafluoride gas (SF6)
= 0.0273 mol / 0.1392 mol
mole fraction of sulfur hexafluoride gas (SF6)
= 0.1961
mole fraction of sulfur hexafluoride gas (SF6)
= 0.196 ( 3 significant digits) i.e the answer
similarly
mole fraction of chlorine pentafluoride gas (ClF5)
= No. of moles of chlorine pentafluoride gas (nClF5) /
Total no. of moles present in 10.00 L tank (ntotal)
mole fraction of chlorine pentafluoride gas (ClF5)
= 0.1119 mol / 0.1392 mol
mole fraction of chlorine pentafluoride gas (ClF5)
= 0.8038
mole fraction of chlorine pentafluoride gas (ClF5)
= 0.804 ( 3 significant digits) i.e the answer
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