20. Which of the following statements is FALSE? A. The entropy of the universe increases during...
Classify each of the statements as true or false. True False Answer Bank The entropy of a substance increases when a liquid vaporizes to a gas at any temperature. Entropy decreases as the temperature increases. An exothermic reaction is always spontaneous. Product formation is always favored in a reaction with a negative AH° and a negative AS. For an endothermic reaction, a decrease in temperature results in a decrease in the equilibrium constant. A reaction will have an equilibrium constant...
2. Decide whether each of the following statements is true or false. If false, rewrite it to make it true. a. Entropy of the universe increases in all spontaneous reactions. wo False If entropy is bw enough it con be spontaneous, b. Reactions with a negative free energy change (A-Gº <0) are product-favored and occur with rapid transformation of reactants to products. True c. An exothermic reaction will always be spontaneous. I NO when AH is negative the reaction can...
CHANGES IN ENTROPY OF UNIVERSE VS SYSTEM. Evaluating Spontaneity Considering both Entropy and Enthalpy 7. In a spontaneous process, which of the following always increases? a. the entropy of the system b. the entropy of the surroundings c. the entropy of the universe d. the entropy of the system and the universe c. the entropy of the system, surroundings and the universe (Hand S refer to the system), a. AH>0 8. Processes are always spontaneous, regardless of temperature, when and...
Indicate whether each statement is true or false. (a) The entropy of the universe increases for any spontaneous process. (b) The entropy change of the system is equal and opposite that of the surroundings for any irreversible process. (c) The entropy of the system must increase in any spontaneous process. (d) The entropy change for an isothermal process depends on both the absolute temperature and the amount of heat reversibly transferred.
Which of the following statements are true (select ALL that apply) (a) The standard entropy of any compound is greater than 0. (b) For a given compound the entropy of a molecule in the gas phase is higher than in a liquid at the same temperature. (c) In a spontaneous process the entropy of the system always increases (d) In a spontaneous process the entropy of the universe always increases. (e) The reaction entropy is always positive. (f) The standard...
Find the standard entropy of the universe for the following reaction at 298K. CH4(g) + 2 O2(g)----> CO2(g) + 2 H2O (g) Is the reaction spontaneous? Explain.
un plase uansion from a liquid to a gas • an increase in the number of moles of a gas during a chemical reaction EXAMPLE 17.1 Predicting the Sign of Entropy Change Predict the sign of AS for each process: (a) H2O(g) → H2O(1) (b) Solid carbon dioxide sublimes. (c) 2 N2O(g) —> 2 N2(8) + O2(g) SOLUTION (a) Since a gas has a greater entropy than a liquid, the entropy decreases and AS is negative. (b) Since a solid...
Entropy (S) The second factor involved in determining whether or not a process is spontaneous is the change in randomness or entropy (AS). Entropy is represented by the symbol S. Again, experience can help us understand the relationship between entropy and spontaneous processes. If we look at the two drawings below, we can predict which picture represents the stack of marbles "before" and after they are bumped. We expect the stack of marbles (less random, lower entropy) to be the...
Its True or False 44. When this reaction is carried out at constant volume at room Tieu out at constant volume at room temperature with 1 mole of Din and sufficient oxygen, the reaction mixture gives off 1,516,000 joules of heat to its surroundings. 45. The entropy of a substance is greater as a liquid than as a solid. 46. The entropy of a substance is greater as a gas than as a liquid. 47. All reactions become more spontaneous...
Which of the following processes would you expect to produces the greatest increase in the entropy of a pure substance that is heated from absolute zero to a temperature somewhat above its boiling point. heating the liquid melting the solid heating the gas heating the solid vaporizing the liquid