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18. Consider a buffer solution containing HNO, and KNO, where the concentration of HNO2 is double the concentration of KNO,.
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Answer #1

18.

Correct option: a

HNO2 is an is a weak acid. Therefore, it partially dissociates in water. On addition of a strong base, HNO2 will convert to KNO2. KNO2 is a salt and it completely dissociates in water. Hence, the nitrite ion concentration will increase if a strong base is added.

Option b is incorrect as pH = pKa when [KNO2] = [HNO2]. But here, [HNO2] = 2 x [KNO2].

Option c is incorrect as pKa of an acid is a constant.

Already the solution has more concentration of acid. Hence, addition of a strong acid will diminish the buffer capacity by converting KNO2 to HNO2. Hence, option d is incorrect.

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