Problem of the Day 16 1. (6 pts) For the following pair of compounds determine if...
Classify the following pair of compounds as the same compound, enantiomers, diasteromers, constitutional isomers, or not isomeric. Also, select the correct IUPAC name, including the correct (R) or (S) designation, for each. same compound enantiomers diastereomers constitutional isomers not isomeric The correct IUPAC names are: Compound I: (3S, 4S)-3,4-dimethylheptane, Compound II: (3S, 4S)-3,4-dimethylheptane Compound I: (3R, 4S)-3,4-dimethylheptane, Compound II: (3S, 4S)-3,4-dimethylheptane Compound I: (3R, 4S)-3,4-dimethylheptane, Compound II: (3S, 4S)-3,4-dimethylheptane Compound I (3S, 4S)-3,-4-dimethylheptane, Compound II: (3R, 4S)-3,4dimethy/heplane
Classify the following pair of compounds as the same compound, enantiomers, diastereomers, constitutional isomers, or not isomeric. Also, select the correct IUPAC name, including the correct (R) or (S) designation, for each. same compound enantiomers diastereomers constitutional isomers not isomeric The correct IUPAC names are: Compound I: (2S, 3S)-1, 2, 3-tribromobutane, Compound II: (2R, 3S)-1, 2, 3-tribromobutane Compound I: (2R, 3S)-1, 2, 3-tribromobutane, Compound II: (2S, 3S)-1, 2, 3-tribromobutane Compound I: (2R.3RH, 2, 3-tribromobutane, Compound II: (2S, 3R)-1, 2, 3-tribromobutane...
Determine whether the following molecules are idenitical,
constitutional isomers, enantiomers, or diastereomers.
Problem 1: Continued. n OH OH OH CI Cl C V. AA OH OH aa. bb. Et H H. H- Me Me ee. CH3 CH3 H CI CItH H H dd. HH CH3 CH3 ff
Which of the following terms best describes the pair of compounds shown: enantiomers, diastereomers, constitutional isomers, the same compounds, different Compounds, or cis-trans (geometric) isomers? 8. (3 pts) CI MOH OH 9. (3 pts) CHO COOH CHO H H -CH, HYCH.CH CHE H3CH2C- -Η COOH 10. (3 pts) OH HO. CH,OH HO OH HO "CH OH OH
age 7 19. The reaction of CH, CH, CCH, CH, with H,/Ni forms a. pentane. b. one particular chiral pentanol. c. an equimolecular mixture of two chiral pentanols . d. one achiral pentanol. e. no product. 20. The p-orbital of a methyl radical carbon, CH,, Contains how many electrons? a. 1 b. 2 e. 3 d. 4 e. 0 21. (2R, 35)-2,3-Dichlorobutane and (25, 3R) -2,3-dichlorobutane are: a. enantiomers b. diastereomers e. identical d. conformational isomers e. constitutional isomers 22....
5. (3 pts each) For the following pairs of molecules, indicate if they are identical different compounds. enantiomers, diastereomers, or constitutional isomers CHE CH H3COH and HOT но — сня нас — Br Hc- Br CH2OH Леон нон он and a нус он Он но- нс сня CI HOBO но and нстве
Extra Credit Worksheet NMU ID 1) Label all the chiral molecules with a circle. Label all meso compounds with a square (3 ps) OH OH 2) Determine the relationship of the following pairs of compounds. Are they identical, enantiomers, diastereomers, constitutional isomers or non-Isomeric different compounds? (4 ps) H internetu papra H-CH-CH Br+H CHE (d) 3) Draw the structures for the following compounds: (3 ps) (R. Z)-4-Ethyl-2-methylhept-5-en-3-one (S)-2-methyl-N-propylpentanamide 4) Give the IUPAC name corresponding to the following structure (Label the...
Question 9 15 pts Determine the relationship between each set of structures Set 1: identical Set 2: constitutional isomers Set 3: diastereomers Set 4: diastereomers Set 5: enantiomers 2 OH OH OH e HO... г - 2 ОН ОН ОН Но... 3 ОН Н. СІ НО, CI нс H нс ОН ОН H 5 н- H CHO -ОН ОН CH2OH CHO но- -Н Н- -ОН Сн,ОН Е.
5) (8 pts) Arrange the following compounds from most acidic through neutral to most basic. Briefly explain your reasoning. 7) (15 pts) a) Write out the 3-step arrow pushing mechanism showing how 1-pentene is hydrated to make 2-pentanol. b) Draw the other 2 alkenes (don't forgel cis/trans isomers!) that could also be hydrated to make 2-pentanol. Briefly explain why 1-pentene is the best choice. II, II,O a) heat Acidic Neutral Basic 6) (18 pts) Consider the Fischer projections of the...
6. Provide the IUPAC names for the compounds below Name: 7. Draw the following: cis-1-isobutyl-2-propyleyclopentane 8. Label the indicated atoms in the structure below as 1º, 2º, 3º, or 4º. PB A A B co 9. Draw Newman projections for the day-diethylane about the C4CS bond, Circle the most stable conforme if you need additional space, please feel free to the backside of this paper 10. Draw the chair conformation and ring-flip for the given compound. Calculate the sterie strain...