Let's see percent dissociation of phenol =
Ka=1.3x 10 -10
C6H5OH + H2O
C6H5 O- +
H3O+
Remarks | conc. (C6H5OH) | conc.C6H5O- | conc . H3O+ | |
Initial | 0.10 M | 0 | 0 | |
Conc. | -X | +X | +X | |
Equilibrium | 0.10M -X | X | X | |
Based on above equation ,
Ka= (C6H5O-) x (H3O+) / (C6H5OH)
= ( x2)/ (0.10 -x)
We know that Ka= 1.3 x 10-10
by putting values ,
So , (x2) / (0.10 -x) = 1.3 x 10 -10
# But (0.10 -x )= very small ,so value of' x' can be neglected .
(x2) = (0.10 x 1.3 x 10-10)
(x2) = 0.13 x 10-12
( X) = 0.3605 x 10-6 M
But here we have to calculate percent dissociation =
= (amount dissociated ( M)/ (initial concentration( M) x 100
= (0.3 x 10-6 M ) / (0.1M) x100
=0.003 %
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