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4. One half cell in a Galvanic cell is constructed from a silver wire dipped into a silver nitrate solution with unknown conc

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Answer #1

4) Zn + 2Ag+ -> 2Ag + Zn​​​​​2+

E°cell = E°cathode - E°anode = E°(Ag+/Ag) - E°(Zn2+/Zn)

= 0.80-(-0.76) = 1.56 V

Ecell = E°cell - 0.059/n log([Zn 2+]/[Ag+]2)

1.48 = 1.56 - 0.059/2 log(1/[Ag+]2)

log[Ag+]2 = (1.48-1.56)×2/0.059 = -2.71

[Ag+]2 = 10-2.71 = 0.00194

[Ag+] = √(0.00194)

= 0.044 M

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