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Chem 3441 Substitution and Elimination Practice Determine the products and indicate the type of reaction o...
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of...
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of the major organic product and indicate the predominant mechanism (S1, S2, E1, or E2) of each reaction KOC(CH) CH:CH-CH:CH BY (CH3),COH, 82°C 9 CH CH CH CH Br Na SCH CH,OH,0°C Nå SCH.CH DMF, 0°C 4 CHI - NaNO, sc CH CH3-Cors HO 22°C CH CH CH,OH 22°C K®SC(CH3) (CH3),COH, 82°C CHẠI • CH,SH 43°C масH,CH, CH,CHOH, 78°C CH H20 22°C Nясн, CH,OH, 0°C
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the st...
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of the major organic product and indicate the predominant mechanism (Syl, SN2, El. or E2) of each reaction. къс(Снь. CH CH CH CH Br (сн),сон, 82с масн, CH3CH2CH2CH Br CHOH, Pc Всньсн, DMF,0°C сны + NaNO3 5°C CH, Сн,-с-отз НО 22°C CH CHOH 22°C кос(CH))). (CH)))соң, бес CHI + CHISH 43°C - месн,CH, CH,CHAOH, 78° с Н,0 22° C AB NACH CH,OH, O°C
3. Shown below are a series of reactions. Predict the major product for each of them....
3. Shown below are a series of reactions. Predict the major product for each of them. Remember, you will need to first decide whether the reaction occurs by an SN2, SN1, E2, or E1 before you can determine what the product will be. Label each as SN2, SN1, E2, or E1. Hint: First decide whether S2/E2 or S1/E1 is favored, and then decide whether the reaction pathway goes by a substitution or elimination reaction. SN2 / SN1 E2/E1 Na DMSO,rt...
determine the products and indicate the type of reaction CH3CH20 Na CH2CH3OH, 80 °C H2O A...
determine the products and indicate the type of
reaction
CH3CH20 Na CH2CH3OH, 80 °C H2O A NaOMe Br CH3OH, 20 °C CH3SH 40 °C Answer the following questions
2. When (1R, 2R)-1-bromo-2-methylcyclohexane reacts with lithium methoxide in methanol, both substitution and elimination reactions occur...
2. When (1R, 2R)-1-bromo-2-methylcyclohexane reacts with lithium methoxide in methanol, both substitution and elimination reactions occur to produce three unique products. What are the structures of the three products produced by this reaction? sepenbare CHOLE сно CH3 3. When (R)-3-mesyl-3-ethyloctane reacts with potassium hydroxide in aqueous THF elimination occurs to produce three unique alkene products. What are the structures of the three products produced by this reaction? MsOCH.CH HOK THF/H20 4. When (S)-2-fluoro-2-iodobutane reacts with hydroxide ion in aqueous THF,...
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3...
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3 CH3-CH=C-CH3 + H20 – CH3-CH2-C-CH3 OH CH3-CH2-CH=CH2 + HCI → CH3-CH2-CH-CH3 CI CH3-CH-CH2-CH3 + CH3-CH=CH-CH3 + HBr Br
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction OH CH2-CH...
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction OH CH2-CH + HCN– CH3-CH-CN CH3-CH2-CH2-OH + HBr – CH3-CH2-CH2-Br + H2O CH3-CH=CH-CH3 + HBr – CH3-CH-CH2-CHz Br
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction CH3-CH2-CH2-CH3 +...
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction CH3-CH2-CH2-CH3 + Cl2 → CH2-CH2-CH2-CH3 + HCI CI CH3-CH=CH-CH3 + Cl2 → CH3-CH-CH-CH3 CICI CH3-CH2-CH-CH3 - CH3-CH2-CH=CH2 + HCI
3 & 4 please Draw all possible El elimination products and indicate which alkene is the...
3
& 4 please
Draw all possible El elimination products and indicate which alkene is the major product: CH3OH CH3 a) HC-C-ci CH3 CH3CH2OH CH3C430H CH3CH2OH Br CH3CH2OH I X ORSOGON CH3OH Br brow all possible E2 elimination products and indicate which okene is the major product CH, ON CH, OH CHÚCHONa CH,CH OH CHÚCH ONa CH,CH, OH CH3CH2ONa d YoX CH₂CH₂OH CH,CH OH (CH3),COH TONE CH,(CH)CH,OH CHCH,ONa CH,CH,OH CH,CH, CH,CH,ONa CH,CH, OH CH,
Organic chem please help 3. Each of the following reactions gives a substitution product. Identify the...
Organic chem please help
3. Each of the following reactions gives a substitution product. Identify the major product in each case and indicate whether the reaction is likely to proceed via a bimolecular (SN2) or a unimolecular (SN1) mechanism. (8 pts) SO2CF3 Nal a) acetone CH3OH b) OMs 80% H2O CH3CH2OH c) Br NaCN DMF d)
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of the major organic product and indicate the predominant mechanism (S1, S2, E1, or E2) of each reaction KOC(CH) CH:CH-CH:CH BY (CH3),COH, 82°C 9 CH CH CH CH Br Na SCH CH,OH,0°C Nå SCH.CH DMF, 0°C 4 CHI - NaNO, sc CH CH3-Cors HO 22°C CH CH CH,OH 22°C K®SC(CH3) (CH3),COH, 82°C CHẠI • CH,SH 43°C масH,CH, CH,CHOH, 78°C CH H20 22°C Nясн, CH,OH, 0°C
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of the major organic product and indicate the predominant mechanism (Syl, SN2, El. or E2) of each reaction. къс(Снь. CH CH CH CH Br (сн),сон, 82с масн, CH3CH2CH2CH Br CHOH, Pc Всньсн, DMF,0°C сны + NaNO3 5°C CH, Сн,-с-отз НО 22°C CH CHOH 22°C кос(CH))). (CH)))соң, бес CHI + CHISH 43°C - месн,CH, CH,CHAOH, 78° с Н,0 22° C AB NACH CH,OH, O°C
3. Shown below are a series of reactions. Predict the major product for each of them. Remember, you will need to first decide whether the reaction occurs by an SN2, SN1, E2, or E1 before you can determine what the product will be. Label each as SN2, SN1, E2, or E1. Hint: First decide whether S2/E2 or S1/E1 is favored, and then decide whether the reaction pathway goes by a substitution or elimination reaction. SN2 / SN1 E2/E1 Na DMSO,rt...
determine the products and indicate the type of
reaction
CH3CH20 Na CH2CH3OH, 80 °C H2O A NaOMe Br CH3OH, 20 °C CH3SH 40 °C Answer the following questions
2. When (1R, 2R)-1-bromo-2-methylcyclohexane reacts with lithium methoxide in methanol, both substitution and elimination reactions occur to produce three unique products. What are the structures of the three products produced by this reaction? sepenbare CHOLE сно CH3 3. When (R)-3-mesyl-3-ethyloctane reacts with potassium hydroxide in aqueous THF elimination occurs to produce three unique alkene products. What are the structures of the three products produced by this reaction? MsOCH.CH HOK THF/H20 4. When (S)-2-fluoro-2-iodobutane reacts with hydroxide ion in aqueous THF,...
Classify each of the following organic reactions. Substitution Addition Elimination Type of Reaction Reaction CH3 CH3 CH3-CH=C-CH3 + H20 – CH3-CH2-C-CH3 OH CH3-CH2-CH=CH2 + HCI → CH3-CH2-CH-CH3 CI CH3-CH-CH2-CH3 + CH3-CH=CH-CH3 + HBr Br
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction OH CH2-CH + HCN– CH3-CH-CN CH3-CH2-CH2-OH + HBr – CH3-CH2-CH2-Br + H2O CH3-CH=CH-CH3 + HBr – CH3-CH-CH2-CHz Br
Classify each of the following organic reactions. Substitution Elimination Addition Type of Reaction Reaction CH3-CH2-CH2-CH3 + Cl2 → CH2-CH2-CH2-CH3 + HCI CI CH3-CH=CH-CH3 + Cl2 → CH3-CH-CH-CH3 CICI CH3-CH2-CH-CH3 - CH3-CH2-CH=CH2 + HCI
3
& 4 please
Draw all possible El elimination products and indicate which alkene is the major product: CH3OH CH3 a) HC-C-ci CH3 CH3CH2OH CH3C430H CH3CH2OH Br CH3CH2OH I X ORSOGON CH3OH Br brow all possible E2 elimination products and indicate which okene is the major product CH, ON CH, OH CHÚCHONa CH,CH OH CHÚCH ONa CH,CH, OH CH3CH2ONa d YoX CH₂CH₂OH CH,CH OH (CH3),COH TONE CH,(CH)CH,OH CHCH,ONa CH,CH,OH CH,CH, CH,CH,ONa CH,CH, OH CH,
Organic chem please help
3. Each of the following reactions gives a substitution product. Identify the major product in each case and indicate whether the reaction is likely to proceed via a bimolecular (SN2) or a unimolecular (SN1) mechanism. (8 pts) SO2CF3 Nal a) acetone CH3OH b) OMs 80% H2O CH3CH2OH c) Br NaCN DMF d)
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