Acyl peroxides are commonly used as initiators in radical processes but react in interesting ways in absence of a substrate

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Acyl peroxides are commonly used as initiators in radical processes but react in interesting ways in absence of a substrate

6) Acyl peroxides are commonly used as initiators in radical processes but react in interesting ways in absence of a substrate. Propose a complete mechanism that explains the following decomposition.

7) Halogen abstraction is preferred over hydrogen abstraction by tin radicals (R₃Sn·). Propose a complete mechanism for the following transformation:

8) The benzylic bromination of A is expected to give mainly compound B but, in practice, product C is the major product. Explain the formation of product C using a reasonable mechanism.

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Acyl peroxides are commonly used as initiators in radical processes but react in interesting ways in absence of a substrate

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Acyl peroxides are commonly used as initiators in radical processes but react in interesting ways in absence of a substrate