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13. Based on the energy diagram below, the free energy of activation the reaction is represented...
HELP by the 14. The addition of a reagent to the face of the compound will...
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by the 14. The addition of a reagent to the face of the compound will produce a n enantiomer An Senantiomer e) An achiral compound d) e) AB 15. How many chirality centers are present in the compound below? OH Artemimi Name the following compound. 2 5 a) (-methylcyclobutyl-2-propane b) 1-sopropyl-2-methylcyclobutane c)2.propyl 1-methylcyclopropane d) 2-methyl-3.6 cycloheptane e) 1-methyl-2-propylcyclobutane 17. Which of the following is the intermediate from the chlorination of cyclopentane? Cyclopentane . a → Chlorocyclopentane ca) (6) (c)...
Based on the energy diagram below, the free energY of the reaction is represented as 13....
Based on the energy diagram below, the free energY of the reaction is represented as 13. de Energy C. Reaction Progness e) A-B A b) в d) D 14. The addition of a reagent to the si face of the a compound will produce a) An S enantiomer c) A racemic mixture b) An R enantiomer d) A meso compound e) An achiral compound How many chirality centers are present in the compound below? 15. C1 a) 1 b) 2...
1. Which of the following molecules has the lowest strain energy? a. Cyclobutane b. Cyclohexane c. Cycloheptane d....
1. Which of the following molecules has the lowest strain energy? a. Cyclobutane b. Cyclohexane c. Cycloheptane d. Cyclopropane 2. Which of the following arranges the groups in order of decreasing priority according to the sequence rules? a. CH3 > CH2CH3 > CH2OH > CO2H c. CH2OH > CO2H > CH2CH3 > CH3 b. CH3 > CH2CH3 > CO2H >CH2OH d. CO2H > CH2OH > CH2CH3 > CH3 3. Which of the following structures represent a meso compound? a. b....
a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments) to calcula...
a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments) to calculate the energy difference between the two chair conformations of the compound below. b. Specify substituent positions axial or equatorial) in the more stable chair. c. Estimate the percent of the more stable chair at equilibrium at 25°C. (To determine the percent of the more stable chair at equilibrium, first calculate Keq, and then use this value to find the percentage.) A CH3...
a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments)...
a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments) to calculate the energy difference between the two chair conformations of the compound below. b. Specify substituent positions (axial or equatorial) in the more stable chair. c. Estimate the percent of the more stable chair at equilibrium at 25°C. (To determine the percent of the more stable chair at equilibrium, first calculate Keq, and then use this value to find the percentage.) OH H3C...
26) Name the following compound. CH3 H2C=CH-CH2CHCH: A) 1,1-dimethyl-3-butane B) 4-methyl-1-pentene C) hexene D) 2-methyl-4-pentene E)...
26) Name the following compound. CH3 H2C=CH-CH2CHCH: A) 1,1-dimethyl-3-butane B) 4-methyl-1-pentene C) hexene D) 2-methyl-4-pentene E) 2-methylpentene 27) Name the following compound. CI A) 2,3,5-trichlorobenzene B) trichlorostyrene C) 1,3,4-trichlorobenzene D) 1,3,4-trichlorohexene E) 1,2,4-trichlorobenzene 28) Identify the formula for an alkene. A) CnH2n+4 B) CnH2n+2 C) CnH2n D) CnH2n-4 E) CnH2n-2 29) Name the following compound. A) 1,4-bromocyclohexene B) 1,4-dibromobenzene C) 3,6-dibromobenzene D) 2,5-dibromobenzene E) 2,5-dibromocyclohexene 30) Name the following compound. CECH CH,CH,CHCH A) 2-ethynebutane B) 3-methyl-1-pentyne C) 3-methyl-4-pentyne D) 3-ethyl-1-butyne...
Ho for the pre c! . Given the bond dissociation energies below in Kcal/mol, estimate the ano forth (CH),CH-CI step...
Ho for the pre c! . Given the bond dissociation energies below in Kcal/mol, estimate the ano forth (CH),CH-CI step . CHCI c) 40 kcal/mol (CH.J.CH a) +22 kcal/mol b)-22 kcal/mol e) -45 kcal/mol he major monobrominated product that results from when methylcyclopentane is subjected d) +45 kcal/mol c) a tertiary halide radical bromination is b) a secondary halide e) bromomethane a) A primary halide d) A quaternary halide 3. Which of the following is a termination a) Cl +...
Strain Energy Increments Strain Energy for Alkanes Interaction/Compound kJ/mol kcal/ 4.0 H: Heclipsing 1.0 H: CH3...
Strain Energy Increments Strain Energy for Alkanes Interaction/Compound kJ/mol kcal/ 4.0 H: Heclipsing 1.0 H: CH3 eclipsing 5.8 1.4 CH3 : CH3 eclipsing 11.0 2.6 gauche butane 3.8 0.9 cyclopropane 115 27.5 cyclobutane 110 26.3 cyclopentane 26.0 6.2 6.3 cycloheptane 26.2 cyclooctane 40.5 9.7 Axial Strain Energies for Monosubstituted Cyclohexanesab This table gives the sum of the values for the 1,3 diaxial interactions of the substituent with two hydrogen atoms. kJ/mol kcal/mol Substituent(solvent) -CH3 1.7 7.3 CH2CH3 7.5 1.8 -CH(CH3)2...
Strain Energy Increments Strain Energy for Alkanes Interaction / Compound kJ/mol kcal/mol H: Heclipsing 4.0 1.0 H: CH3...
Strain Energy Increments Strain Energy for Alkanes Interaction / Compound kJ/mol kcal/mol H: Heclipsing 4.0 1.0 H: CH3 eclipsing 5.8 1.4 CH3 : CHз eclipsing 11.0 2.6 gauche butane 3.8 0.9 cyclopropane 27.5 115 cyclobutane 110 26.3 cyclopentane 26.0 6.2 cycloheptane 26.2 6.3 cyclooctane 40.5 9.7 Ln Axial Strain Energies for Monosubstituted Cyclohexanesa,b This table gives the sum of the values for the 1,3 diaxial interactions of the substituent with two hydrogen atoms. Substituent(solvent) К/mol kcal/mol -CНз 7,3 1,7 -CH-CHз...
1. What is the IUPAC name for the following compound? CH3 CI CH3-CH-C- CH-CH CH3 CH3...
1. What is the IUPAC name for the following compound? CH3 CI CH3-CH-C- CH-CH CH3 CH3 A) 4-chloro-4,5-dimethyl-2-hexene B) 3-chloro-1,3,4-trimethyl-1-pentene C) 3-chloro-2,3-dimethyl-4-hexene D) 3-chloro-2,3,5-trimethyl-4-pentene E) 3-chloro-1,3,4,4-tetramethyl-1-butene 2. Name the following compound. CH-CH2 CH,CH CH CCH H-CH A) 2,2-diethylpenatane B) 2,2-diethylpentene C) 4-ethyl-4-methyl-5-hexene D) 3-ethyl-3-methyl-1-hexene E) 4-ethyl-4-methylhexane 3. Name the following compound. CH CH CH, CH,CH CC CH CH2CH CH A) 3-butyl-3-propyl-1-pentyne B) 3-butyl-3-propyl-4-pentyne C) 3-ethyl-3-propyl-1-heptyne D) 5-ethyl-5-propyl-6-heptyne E) 3-ethyl-3-butyl-1-hexyne
HELP
by the 14. The addition of a reagent to the face of the compound will produce a n enantiomer An Senantiomer e) An achiral compound d) e) AB 15. How many chirality centers are present in the compound below? OH Artemimi Name the following compound. 2 5 a) (-methylcyclobutyl-2-propane b) 1-sopropyl-2-methylcyclobutane c)2.propyl 1-methylcyclopropane d) 2-methyl-3.6 cycloheptane e) 1-methyl-2-propylcyclobutane 17. Which of the following is the intermediate from the chlorination of cyclopentane? Cyclopentane . a → Chlorocyclopentane ca) (6) (c)...
Based on the energy diagram below, the free energY of the reaction is represented as 13. de Energy C. Reaction Progness e) A-B A b) в d) D 14. The addition of a reagent to the si face of the a compound will produce a) An S enantiomer c) A racemic mixture b) An R enantiomer d) A meso compound e) An achiral compound How many chirality centers are present in the compound below? 15. C1 a) 1 b) 2...
1. Which of the following molecules has the lowest strain energy? a. Cyclobutane b. Cyclohexane c. Cycloheptane d. Cyclopropane 2. Which of the following arranges the groups in order of decreasing priority according to the sequence rules? a. CH3 > CH2CH3 > CH2OH > CO2H c. CH2OH > CO2H > CH2CH3 > CH3 b. CH3 > CH2CH3 > CO2H >CH2OH d. CO2H > CH2OH > CH2CH3 > CH3 3. Which of the following structures represent a meso compound? a. b....
a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments) to calculate the energy difference between the two chair conformations of the compound below. b. Specify substituent positions axial or equatorial) in the more stable chair. c. Estimate the percent of the more stable chair at equilibrium at 25°C. (To determine the percent of the more stable chair at equilibrium, first calculate Keq, and then use this value to find the percentage.) A CH3...
a. Use strain energy increments in the OWL Table Reference (see References button, Strain Energy Increments) to calculate the energy difference between the two chair conformations of the compound below. b. Specify substituent positions (axial or equatorial) in the more stable chair. c. Estimate the percent of the more stable chair at equilibrium at 25°C. (To determine the percent of the more stable chair at equilibrium, first calculate Keq, and then use this value to find the percentage.) OH H3C...
26) Name the following compound. CH3 H2C=CH-CH2CHCH: A) 1,1-dimethyl-3-butane B) 4-methyl-1-pentene C) hexene D) 2-methyl-4-pentene E) 2-methylpentene 27) Name the following compound. CI A) 2,3,5-trichlorobenzene B) trichlorostyrene C) 1,3,4-trichlorobenzene D) 1,3,4-trichlorohexene E) 1,2,4-trichlorobenzene 28) Identify the formula for an alkene. A) CnH2n+4 B) CnH2n+2 C) CnH2n D) CnH2n-4 E) CnH2n-2 29) Name the following compound. A) 1,4-bromocyclohexene B) 1,4-dibromobenzene C) 3,6-dibromobenzene D) 2,5-dibromobenzene E) 2,5-dibromocyclohexene 30) Name the following compound. CECH CH,CH,CHCH A) 2-ethynebutane B) 3-methyl-1-pentyne C) 3-methyl-4-pentyne D) 3-ethyl-1-butyne...
Ho for the pre c! . Given the bond dissociation energies below in Kcal/mol, estimate the ano forth (CH),CH-CI step . CHCI c) 40 kcal/mol (CH.J.CH a) +22 kcal/mol b)-22 kcal/mol e) -45 kcal/mol he major monobrominated product that results from when methylcyclopentane is subjected d) +45 kcal/mol c) a tertiary halide radical bromination is b) a secondary halide e) bromomethane a) A primary halide d) A quaternary halide 3. Which of the following is a termination a) Cl +...
Strain Energy Increments Strain Energy for Alkanes Interaction/Compound kJ/mol kcal/ 4.0 H: Heclipsing 1.0 H: CH3 eclipsing 5.8 1.4 CH3 : CH3 eclipsing 11.0 2.6 gauche butane 3.8 0.9 cyclopropane 115 27.5 cyclobutane 110 26.3 cyclopentane 26.0 6.2 6.3 cycloheptane 26.2 cyclooctane 40.5 9.7 Axial Strain Energies for Monosubstituted Cyclohexanesab This table gives the sum of the values for the 1,3 diaxial interactions of the substituent with two hydrogen atoms. kJ/mol kcal/mol Substituent(solvent) -CH3 1.7 7.3 CH2CH3 7.5 1.8 -CH(CH3)2...
Strain Energy Increments Strain Energy for Alkanes Interaction / Compound kJ/mol kcal/mol H: Heclipsing 4.0 1.0 H: CH3 eclipsing 5.8 1.4 CH3 : CHз eclipsing 11.0 2.6 gauche butane 3.8 0.9 cyclopropane 27.5 115 cyclobutane 110 26.3 cyclopentane 26.0 6.2 cycloheptane 26.2 6.3 cyclooctane 40.5 9.7 Ln Axial Strain Energies for Monosubstituted Cyclohexanesa,b This table gives the sum of the values for the 1,3 diaxial interactions of the substituent with two hydrogen atoms. Substituent(solvent) К/mol kcal/mol -CНз 7,3 1,7 -CH-CHз...
1. What is the IUPAC name for the following compound? CH3 CI CH3-CH-C- CH-CH CH3 CH3 A) 4-chloro-4,5-dimethyl-2-hexene B) 3-chloro-1,3,4-trimethyl-1-pentene C) 3-chloro-2,3-dimethyl-4-hexene D) 3-chloro-2,3,5-trimethyl-4-pentene E) 3-chloro-1,3,4,4-tetramethyl-1-butene 2. Name the following compound. CH-CH2 CH,CH CH CCH H-CH A) 2,2-diethylpenatane B) 2,2-diethylpentene C) 4-ethyl-4-methyl-5-hexene D) 3-ethyl-3-methyl-1-hexene E) 4-ethyl-4-methylhexane 3. Name the following compound. CH CH CH, CH,CH CC CH CH2CH CH A) 3-butyl-3-propyl-1-pentyne B) 3-butyl-3-propyl-4-pentyne C) 3-ethyl-3-propyl-1-heptyne D) 5-ethyl-5-propyl-6-heptyne E) 3-ethyl-3-butyl-1-hexyne
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