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QUESTION 6 2NOBr(g) → 2NO(g) + Br2(g) [NOB:](mol =) Rate (mol-1,-1) 0.0450 162 * 10-3 0.0310 7.69 x 10-4 0.0095 7.22 x 10-5 B
0 2
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Answer #1

Let the rate law be:

Rate = k [NOBr]^x

From row 1:

Rate = k [NOBr]^x

1.62*10^-3 = k (0.0450)^x

From row 2:

Rate = k [NOBr]^x

7.69*10^-4 = k (0.0310)^x

Divide 1st equation by 2nd one

1.62*10^-3 / 7.69*10^-4 = (0.0450/0.0310)^x

2.11 = (1.45)^x

(1.45)^2 = (1.45)^x

So,

x = 2

The rate law is:

Rate = k [NOBr]^2

Put values from row 1

1.62*10^-3 mol.L-1.s-1= k (0.0450 mol.L-1)^2

K = 0.800 L.mol-1.s-1

Answer: b

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