need help with 7and8 dont know how to do Propylene oxide (2-methyloxirane or 1,2-epoxypropane) can be...
can you explain this Propylene oxide (2-methyloxirane or 1,2-epoxypropane) can be converted to 1,2-propanediol by the action of either dilute acid or base in water. When optically active (R)-(+)-propylene oxide is used, the 1,2-propanediol obtained from the acid hydrolysis (HO) has an optical rotation opposite from the alkaline hydrolysis (OH, H2O). Write the stepwise mechanism of each hydrolysis that is likely to explain these facts. Use curved arrows to show the flow of electrons. OH Enantiomers но opposite optical rotation...
Hc VCH Draw the organic product formed when CH3CH2CH2OH is treated with each reagent. a H2S04 (180°C) d SOC12, pyridine Ig 1) NaH; 2) CH3CH2Br b NaH e PBr3 h 1) TSCI, pyridine; 2) NaSH c HBr f TsCl, pyridine 3. Draw the organic product formed when l-methylcyclohexanol is treaded with each reagent. In some cases, no reaction occurs. a KH c HBr Te NaHCO3 b Nacid HCI f 1) KH; 2) CH3CH2Br Draw two different routes to each of...
Can yall please check solutions, I am not sure if they are correct thanks СНО ОН Br НО Н NC Compound A Compound B Compound C Compound D СНО Br F CHO HS CHз Compound H Compound E Compound F Compound G Determine if the stereochemistry of each of the above O= True If the R isomer of a molecule has an optical rotation of + 25.7° then the S isomer of the molecule will have an optical rotation of...
9. C (Z-2-hexene d. They are all of equal stability. Choose the most stable alkene among the following a 1-hexene b. (E)-2-hexene 10. What is the relation between an enantiomer's configuration and its specific rotation? (a) Rcompounds usually are dextrorotatory with few exceptions (b) R compounds always are dextrorotatory. (c) There is no relation. (d) R compounds always are levorotatory 11. How many chiral centers are there in tartaric acid, and how many different stereoisomers exist for this acid? он...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...