Solution:
Correct option is B (equal amounts of I and III )
The given reaction is completed in two steps:
1) Epoxidation
2) Acid catalysed ring opening of epoxide.
Thus, H2O attacks from highly hindered side of epoxide which result into the formation of trans-diols. Product I and III are trans diols. Therefore, they will form in equal amounts.
For the following dihydroxylation reaction which of the following statements is correct regarding the expected products?...
Question 30 (2 points) What are the expected major products of the reaction sequence shown below? 1. 03 2. H20 e OH O=C=0 OH II III IV V O a) I and IV Ob) II, III and IV Oc) I and II O d) 1, III and IV Question 31 (2 points) A compound with a molecular formula of C10H1202 has the following 'H NMR spectrum. Which of the following structures is consistent with this spectrum? 2 o OCH2CH2CH3 0...
1. MCPBA 2. H, H20 CH(CH3)2 H3CH2C- OH H- OH CH2CH3 CH(CH3)2 CH(CH3)2 CH(CH3)2 HECH,C- OH HOCH,CH, HOCHCH, HOH HOH H- OH CH2CH2 C H2CH3 CH2CH3 A. I and II B. III and IV c. I and IV D. II and III E. I and 111
Question 12 Which Fischer projection corresponds with the following molecule? Br OH CHO CHO CHO CHO CHO H ОН HO -H HO- Br HO -H -H H- -Br HE -Br Br -H Br -H CH2CH, CH,CH, CH2CH3 CH2CH3 снясно II III IV y ΟΙ O II O III O IV V
18) What is the major organie product of the following reaction? on los, abe O= -CHCOCH 0=C CHỊ CHCOCHE O=C-CH3 CHCOCH HO CH–CH3 C CH2CH3 0 OHCHCOCH MI. So=C-CH₃ A) B) II C) III D) IV E) V 19) What is the major organic product of the following addition? OH CH, CHỊCH • H-CH- (excess) I CH,CH,CHCH IV. CH,CHCH CH OH OH IL OHO CHC-CH CH OH M. A) I HOCH.CH.CH.CH B) II C) III D) IV E) V
Q: which structure beat represents the following disubstituted cuclohexane? Q: which fisher projection corresponds with the following molecule? 8. Whien structure best represents the foliowing disubstituted cyclohexane? Cн CHs H. нс нс CH CHs II d. I V a. b. III е. IV с. 9. Which of the following molecules has the highest melting point? но IV Ш I п d. II III a. e. b. IV I с. 10. Which Fischer projection corresponds with the following molecule? Br HO...
29. Which are the major reaction products of the following reaction, which is carried out in an inert solvent? AICI: solvent NO2 Oló - o 02 a) I and II b) III and IV c) I and IV d) II and III 30. Which is the major product of the following reactions? CH3CI Cl2 K2Cr207 FeCl3 FeCl3 H2SO4 a) para-chlorobenzoic acid b) meta-chlorobenzoic acid c) a mixture of para- and meta-chlorobenzoic acid d) a mixture of ortho- and para-chlorobenzoic acid...
CHM 211 STEREOCHEMISTRY Chapter 5 3. Hexane and 3-methylpentane are examples of: (a) Enantiomers (6) Constitutional isomers (c) Diasercomers (d) Conformers 4. Which of the following is a meso compound? CH CHE CH Htci (a) CH (b) " (d) WH+ CH.CH H- CH.CH Htc CH H 5. Which of the following is NOT true about enantiomer? (a) The have the same boiling point (b) The have the same melting poing (c) The have the same density (d) The have the...
1. MCPBA 2. H*, НО Но н. НО Н Н3СН-Синг СН-СН3 НОН » » » » mCH-CH, OH НО CH2CH3 H. Начин H3CH2COH H3CH, O I and III O II and III
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