Question









1. A solid sample containing some Fe2+ weighs 2.360 g. It required 36.44 mL 0.0244 M KMnO, to titrate the Fe- in the dissolve
2. (2 points) Calculate the percentage of Fe in pure iron(II) ammonium sulfate hexahydrate: (NH4)2[Fe(SO4)2]• 6 H20.
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Answer #1

1)

No. of moles of MnO4- required = molarity x volume

= 0.0244 x 36.44

= 0.889 millimoles

change in oxidation state = 5

change in oxidation state = 1

Thus no. of moles of Fe present = 5 / 1 x 0.889

= 4.45 millimoles

Mass of iron present = 4.45 / 1000 x 56 g / mol

= 0.249 g

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