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3) Mechanism and Reactivity Part 1 The following molecule was treated with a catalytic amount...
When 3-methyl-1-butene is treated with a catalytic amount of BF3 and H2O a cationic polymerization process...
When 3-methyl-1-butene is treated with a catalytic amount of BF3 and H2O a cationic polymerization process occurs, but the expected homopolymer is not formed. Explain in detail with mechanism(s), intermediate structure(s) and the final repeat unit(s).
Question 3. Predict the major products of the reactions below. Draw the full mechanism for the...
Question 3. Predict the major products of the reactions below. Draw the full mechanism for the reactions, using appropriate arrows to indicate electron movement and the full structures of any intermediate(s). Use the mechanism of the reaction to provide a rationale for why the major product formed. OM (1 equivalent) ansole Bry Febr (1 culle brambenzone Fer (1 equivalent Priloromethylbenzene (9 marks) Question 4. Predict the major product from the treatment of 2,5-dibromopyridine with ammonia. Draw the full mechanism for...
predict the products and indicate the relative stereochemistry for the following transformations. When necessary indicate the major product. Me 1. light 2. xylenes, heat Et (d) (4 points) CN xylen...
predict the products and indicate the relative stereochemistry
for the following transformations. When necessary indicate the
major product.
Me 1. light 2. xylenes, heat Et (d) (4 points) CN xylenes, heat Me 2. H30+, heat 3. Me OH Me Me cat p-TsOH, PhH reflux (d) (4 points) Meo OMe 1. AczO, pyridine Meo 2. HO HO OH
Me 1. light 2. xylenes, heat Et (d) (4 points) CN xylenes, heat Me 2. H30+, heat 3. Me OH Me Me cat...
1. Provide the products of the reaction below and a detailed reaction mechanism using curved arrows...
1. Provide the products of the reaction below and a detailed reaction mechanism using curved arrows to indicate the movement of electrons. (a) (b) КОН (c) Note that formation of 4- or 7-membered rings is disfavored. Hiyo KOH acidie workup 2. An interesting problem that involves a bit of review (imines and Grignard chemistry) and application of what you previously learned to a new reaction: The Carbon of an imine functional group (i.e. R.C-NR) is sufficiently electron deficient to be...
please help with organic chemistry! mechanisms? 5) The reaction of 2-bromo-1,1-dimethylcyclohexane with methanol gives the following...
please help with organic chemistry! mechanisms?
5) The reaction of 2-bromo-1,1-dimethylcyclohexane with methanol gives the following products. Please provide a detailed explanation to the formation of each product. You should use structures of intermediates in your answer. (8 points). осн, CH,он OCH Br + 6) There are a variety of isomeric 1,2,3,4,5,6-hexachlorocyclohexanes, but one of them does not react with CH3CH20' to give an elimination product. Provide the structure of this compound and briefly explain why it does not react...
help please Incorrect Mechanism (The mechanism is for the formation of the 1,4 product. Please ignore...
help please
Incorrect Mechanism (The mechanism is for the formation of the 1,4 product. Please ignore the 1,2 product). + Br + H-Br R Br Assignment 6: Mechanism Correction On a page titled Incorrect Mechanism print the incorrect mechanism provided for your molecule on Blackboard. For the mechanism you will focus on the reaction of the portion of the molecule drawn only (not the R part). The molecule will be drawn with R groups so that you may ignore other...
1. Consider the following substituted alkanes. Indicate if the molecule would prefer to undergo an SN1...
1. Consider the following substituted alkanes. Indicate if the molecule would prefer to undergo an SN1 reaction, an reaction, BOTH S1/E1 or neither: -BOK 2. Briefly explain why you selected what you did for question 1a, 1b, and 1c. 3. Provide the missing reactant(s) or product(s) as necessary for the following Sy1 reactions. Be sure to use wedges/dashes to indicate stereochemistry where relevant. осн. HOCH,CH, heat 4. Draw the complete mechanism for the following reaction. Include all lone pairs, formal...
1. Following the guide on page 154, give the mechanism for the E2 reaction shown below....
1. Following the guide on page 154, give the mechanism for the E2 reaction shown below. КОН CH3 H3CH2CH2C-C-C-CH2CH2CH3 H CH3 H2CH2CH2C-C-C-CH2CH2CH3 H BI 2. Each reaction shown below (a and b) produces three elimination products. Draw all possible products formed. Write "major" under the Zaitsev product. concentrated acid strong base
help Thank you 4. (10 pts) Draw all possible products for the following reaction including stereoisomers....
help Thank you
4. (10 pts) Draw all possible products for the following reaction including stereoisomers. Note that the addition occurs through a "syn" mechanism. Is the product solution optically active (yes or no)? 1. BAHATHF 2. NaOH, HO (8 pts) Provide a complete mechanism for the reaction below and include lone-pairs of electrons and formal charges. Show all products formed including stereoisomers. Is the product solution optically active (yes or no)? Bras 11. (8 pts) Draw all four regiochemical...
A. Double bonds that are connected by a single bond are said to be conjugated. For...
A. Double bonds that are connected by a single bond are said to be conjugated. For each molecule below, indicate how many conjugated double bonds are present in each molecule. HO OH bro HO B. One feature that distinguishes conjugated dienes from isolated dienes is that the C-C bond joining the two double bonds is unusually short. For each of the molecules in Part A, indicate which C-C single bond(s) might be shorter than expected. C. Some reactions of conjugated...
Question 3. Predict the major products of the reactions below. Draw the full mechanism for the reactions, using appropriate arrows to indicate electron movement and the full structures of any intermediate(s). Use the mechanism of the reaction to provide a rationale for why the major product formed. OM (1 equivalent) ansole Bry Febr (1 culle brambenzone Fer (1 equivalent Priloromethylbenzene (9 marks) Question 4. Predict the major product from the treatment of 2,5-dibromopyridine with ammonia. Draw the full mechanism for...
predict the products and indicate the relative stereochemistry
for the following transformations. When necessary indicate the
major product.
Me 1. light 2. xylenes, heat Et (d) (4 points) CN xylenes, heat Me 2. H30+, heat 3. Me OH Me Me cat p-TsOH, PhH reflux (d) (4 points) Meo OMe 1. AczO, pyridine Meo 2. HO HO OH
Me 1. light 2. xylenes, heat Et (d) (4 points) CN xylenes, heat Me 2. H30+, heat 3. Me OH Me Me cat...
1. Provide the products of the reaction below and a detailed reaction mechanism using curved arrows to indicate the movement of electrons. (a) (b) КОН (c) Note that formation of 4- or 7-membered rings is disfavored. Hiyo KOH acidie workup 2. An interesting problem that involves a bit of review (imines and Grignard chemistry) and application of what you previously learned to a new reaction: The Carbon of an imine functional group (i.e. R.C-NR) is sufficiently electron deficient to be...
please help with organic chemistry! mechanisms?
5) The reaction of 2-bromo-1,1-dimethylcyclohexane with methanol gives the following products. Please provide a detailed explanation to the formation of each product. You should use structures of intermediates in your answer. (8 points). осн, CH,он OCH Br + 6) There are a variety of isomeric 1,2,3,4,5,6-hexachlorocyclohexanes, but one of them does not react with CH3CH20' to give an elimination product. Provide the structure of this compound and briefly explain why it does not react...
help please
Incorrect Mechanism (The mechanism is for the formation of the 1,4 product. Please ignore the 1,2 product). + Br + H-Br R Br Assignment 6: Mechanism Correction On a page titled Incorrect Mechanism print the incorrect mechanism provided for your molecule on Blackboard. For the mechanism you will focus on the reaction of the portion of the molecule drawn only (not the R part). The molecule will be drawn with R groups so that you may ignore other...
1. Consider the following substituted alkanes. Indicate if the molecule would prefer to undergo an SN1 reaction, an reaction, BOTH S1/E1 or neither: -BOK 2. Briefly explain why you selected what you did for question 1a, 1b, and 1c. 3. Provide the missing reactant(s) or product(s) as necessary for the following Sy1 reactions. Be sure to use wedges/dashes to indicate stereochemistry where relevant. осн. HOCH,CH, heat 4. Draw the complete mechanism for the following reaction. Include all lone pairs, formal...
1. Following the guide on page 154, give the mechanism for the E2 reaction shown below. КОН CH3 H3CH2CH2C-C-C-CH2CH2CH3 H CH3 H2CH2CH2C-C-C-CH2CH2CH3 H BI 2. Each reaction shown below (a and b) produces three elimination products. Draw all possible products formed. Write "major" under the Zaitsev product. concentrated acid strong base
help Thank you
4. (10 pts) Draw all possible products for the following reaction including stereoisomers. Note that the addition occurs through a "syn" mechanism. Is the product solution optically active (yes or no)? 1. BAHATHF 2. NaOH, HO (8 pts) Provide a complete mechanism for the reaction below and include lone-pairs of electrons and formal charges. Show all products formed including stereoisomers. Is the product solution optically active (yes or no)? Bras 11. (8 pts) Draw all four regiochemical...
A. Double bonds that are connected by a single bond are said to be conjugated. For each molecule below, indicate how many conjugated double bonds are present in each molecule. HO OH bro HO B. One feature that distinguishes conjugated dienes from isolated dienes is that the C-C bond joining the two double bonds is unusually short. For each of the molecules in Part A, indicate which C-C single bond(s) might be shorter than expected. C. Some reactions of conjugated...
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