1. Consider the following substituted alkanes. Indicate if the molecule would prefer to undergo an SN1...
Multistep reaction mechanisms Group ActivityTreating (S)-2-butanol with HBr results in the following two step reaction: Step 1: CH3CH(OH)CH2CH3 + HBr ⇌ CH3CH(OH2)CH2CH3+ + Br-Step 2: CH3CH(OH2)CH2CH3+ + Br- ⇌ CH3CH(Br)CH2CH3 + H2ODraw a mechanism for each step. Draw structures for all reactants and products, including correct stereochemistry (wedges and dashes). Show all the curved arrows in each step, and label each curved arrow according to whether it represents proton transfer, loss of a leaving group, nucleophilic attack, or carbocation rearrangement.
1. For the following Alkyl halide indicate which position will react under SN1 reaction conditions and under SN2 reaction conditions. Explain your answer. mer 2. Draw the complete mechanism and the products for of the following SN1 reaction paying close attention to stereochemistry. H3C CI CH OH CH2CH3 општироотип солио 3. Provide the product/s for the following reactions. Indicate if the reactions proceed via an SN1, or SN2 mechanism. Indicate proper stereochemistry if it is applicable. Show the mechanisms NaCN...
Draw the major products in the following SN1 reaction and draw a detailed mechanism for the transformation. Marks will be given for the proper use of arrows. What stereochemical relationship do the products have with each other? Draw your answers as line structures and show stereochemistry of asymmetric centers with wedges and dashes. ОН H2SO4 NaBr
Practice the Skill 16.13 Draw the products for each of the following reactions. Using wedges and dashes, indicate the stereochemistry. If a pair of enantiomers are expected, make sure to draw both enantiomers. 16.13a x Your answer is incorrect. Try again. ОMe OMe Edit
Give only the major organic products, starting materials or conditions for the following reactions. If more than one isomer is possible make sure to clearly indicate both structures. Be sure to indicate the correct stereochemistry of the products (using dashes and wedges or cis/trans) where needed. Write "NR" if no reaction occurs.
4. (26 pts) Draw the products of the following reactions. If more than one product is expected, indicate which would be the major product, if predictable. Include stereochemistry where relevant: NaOEt NaoMe I- BOK NaSH NaOEt NaOH NaOH H2SO4 heat
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. CH₂ Na O=CH₂ Hic Br 2 Draw complete mechanism with arrows for the SNI/E1 mechanism. Check for carbocation rearrangements CH3 + H2O 3. Which is the major product for the following reaction? Y CH + NaOH CH HO HO H₃ CH₂ H₃ HOCH CH₂ H₃ CHE CH₂ CH₂ CH3 CH 4. Name the following including the R/S, E/Z...
1. Draw the product(s) of the following reactions. Include stereochemistry when relevant. If stereoisomers are formed then draw out and label the relationship between your structures. Ph-N3 40°C HN-NH2 SACOMe 150 °C d. CO2CH3 210 °C нсОСН3 In hv ZI 160 °C OBn 85 °C OBn OBno= o 1 equiv. CI K2CO3 heat PhCH N= H 1. LDA (1 equiv.) P 2. Ph Ph 3. aqueous work-up heat EtOH NaOEt 2. Draw the mechanism for the following transformations. I Н...
raw the organic products produced in each of the following reactions. For partial credit, indicate whether the reaction is an E1, E2, S1. or S2 reaction on the line provided. Show stereochemistry when relevant. (19 pts) H₂ CH₂ нстве CH,OH HS acetone CH, Br e 99 cach. 9 CEC-H DMF e KUN DMSO Осн. CH, OH, 50°C
5. (25 Points) Draw all products for the following two reactions. Be sure to indicate stereochemistry if it is relevant. Clearly state whether each product came from an E1, SX1, E2, or S2 reaction. NaOME MeOH, heat