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3. In this experiment we did not add KMnO4 to toluene (aromatic compounds). Addition of KMnO4...
Solubility and Reactivity of Alkanes, Alkenes and Aromatic Compounds Advance Study Form *****There are 2 pages...
Solubility and Reactivity of Alkanes, Alkenes and Aromatic Compounds Advance Study Form *****There are 2 pages to this Advance Study Form ***** 1. a. The structure of cholesterol is shown below. Indicate if cholesterol is saturated or unsaturated. Explain your answer. b. What chemical tests would you run to determine if it saturated or unsaturated? Indicate what color changes you would expect. 2. Why don't we use Cl2 instead of Bra in the test for unsaturation? 3. Predict the product...
We did an experiment called oxidation of toluene. Please help with this example quiz question After...
We did an experiment called oxidation of toluene. Please help with this example quiz question After refluxing the suspension of toluene in alkaline KMnO4, the reaction mixture was treated sequentially with sulfuric acid and oxalic acid to isolate benzoic acid. What was the role of sulfuric acid?
1-3? e-Laboratory Questions-Expa XP 3 Name: Nitration of Aromatic Compounds Due before lab begins. Answer in...
1-3?
e-Laboratory Questions-Expa XP 3 Name: Nitration of Aromatic Compounds Due before lab begins. Answer in space provided. 1. Which is nitrated faster? toluene or nitrobenzene? Explain. 2. Indicate the product formed on (mono) nitration of each of the following compounds: a) Cyanobenzene (benzonitrile) b) toluene c) benzoic acid 3. Why is methyl m-nitrobenzoate formed in this reaction instead of o- and p-? What product would you expect if methyl benzoate underwent dinitration? 4. Methyl-m-nitrobenzoate is an excellent (identification) derivative...
3-5?? e-Laboratory Questions-EXP 3 Nitration of Aromatic Compounds Name: tso ds Due before lab begins. Answer...
3-5??
e-Laboratory Questions-EXP 3 Nitration of Aromatic Compounds Name: tso ds Due before lab begins. Answer in space provided. 1. Which is nitrated faster? toluene or nitrobenzene? Explain. 2. Indicate the product formed on (mono) nitration of each of the following compounds: a) Cyanobenzene (benzonitrile) b) toluene c) benzoic acid. 3. Why is methyl m-nitrobenzoate formed in this reaction instead of o- and p-? What product would you expect if methyl benzoate underwent dinitration? 4. Methyl-m-nitrobenzoate is an excellent (identification)...
5. Iron(III) ions are used as a qualitative test for phenols (aromatic compounds containing an-OH functional group)...
5. Iron(III) ions are used as a qualitative test for phenols (aromatic compounds containing an-OH functional group). (1 point) a. What compound was used as a positive control for the Fe3+ test in this experiment? b. Did the reaction product give a positive or negative test with Fe3+ ions? Explain. 6. Acetic anhydride was used in excess in this experiment. What does this mean, and how was the excess acetic anhydride decomposed at the end of the reaction? (1 point)
Add the following questions to the final report: a) Why does the carbomethoxy group directs the...
Add the following questions to the final report: a) Why does the carbomethoxy group directs the reaction to positions that are meta to it? b) Why the formation of dinitrobenzaote is substantially disfavored ? c) Would you expect small amounts of the ortho and para substituted product? How would you remove them if they are formed ? d) Why does water have a retarding effect on the nitration ? e) Explain why Benzene has lower reactivity in electrophilic addition reactions...
1.) (9 points) Give structures for the following compounds: a) meta-phenylphenol b) 6-benzyl-3-heptanol e) ortho-sec-butyltoluene 2.)...
1.) (9 points) Give structures for the following compounds: a) meta-phenylphenol b) 6-benzyl-3-heptanol e) ortho-sec-butyltoluene 2.) (9 points) Name the following compounds: 3.) (8 points) Label the following molecules as aromatic, anti-aromatic, or non-aromatic. For the ones th aren't aromatic, explain why they are either non-aromatic or anti-aromatic. 0.8 4.) (11 points) For the following electrophilic aromatic substitution reaction: Вт, FeBr; a) Which product is the major one? b) Draw a complete mechanism for the formation of the major product...
EXPERIMENT 20 CSI: SMU Part 2. Synthesis of an Ester. Esters are compounds of the form...
EXPERIMENT 20 CSI: SMU Part 2. Synthesis of an Ester. Esters are compounds of the form RCOOR'. They occur naturally in many plants and animals, and can be synthesized. They have a pleasant aroma usually described as "fruity of flowery". In a Fisher esterification an ester is formed from the reaction of a carboxylic acid and an alcohol with a strong acid as a catalyst. The OH contained in the carboxylic acid group 1s replaced with the alkoxy group (O-R")...
need help with the Molarity of both parts EXPERIMENT 8: AN OXIDATION-REDUCTION TITRATION DATA SHEET 0.2M...
need help with the Molarity of both parts
EXPERIMENT 8: AN OXIDATION-REDUCTION TITRATION DATA SHEET 0.2M 10 m2 Concentration of original KMnO solution Volume of Original KMnO4 solution used Molarity of KNOWN HOCg04 D.ISOM Standardization of KMnO solution. Sample 3 Sample 1 Volume H2C204 11.00ML Initial buret reading (KMnO4) .00 mc Final buret reading (KMnO4) 12.00ML Volume KMnO4 12.00ml Molarity KMnO4 Average (KMnO4) Sample 2 4:00ML 12.00mL 13.5ML . SOL Determination of Unknown Solution Sample 3 Sample 1 4ml Volume...
1. True and False Question (0.5 point per question) a) Carbonyl compounds have higher boiling points...
1. True and False Question (0.5 point per question) a) Carbonyl compounds have higher boiling points than hydrocarbons, but lower boiling points than corresponding alcohols. b) Aldehydes and ketones react with primary amines to form imines and with secondary amines to form enamines. c) Aldehydes and ketones can be oxidized to carboxylic acids. d) Diols can form acetal with the ketone or aldehyde to protect them for selective reduction of the ester. e) The electron-withdrawing group in Wittig reagent does...
Solubility and Reactivity of Alkanes, Alkenes and Aromatic Compounds Advance Study Form *****There are 2 pages to this Advance Study Form ***** 1. a. The structure of cholesterol is shown below. Indicate if cholesterol is saturated or unsaturated. Explain your answer. b. What chemical tests would you run to determine if it saturated or unsaturated? Indicate what color changes you would expect. 2. Why don't we use Cl2 instead of Bra in the test for unsaturation? 3. Predict the product...
1-3?
e-Laboratory Questions-Expa XP 3 Name: Nitration of Aromatic Compounds Due before lab begins. Answer in space provided. 1. Which is nitrated faster? toluene or nitrobenzene? Explain. 2. Indicate the product formed on (mono) nitration of each of the following compounds: a) Cyanobenzene (benzonitrile) b) toluene c) benzoic acid 3. Why is methyl m-nitrobenzoate formed in this reaction instead of o- and p-? What product would you expect if methyl benzoate underwent dinitration? 4. Methyl-m-nitrobenzoate is an excellent (identification) derivative...
3-5??
e-Laboratory Questions-EXP 3 Nitration of Aromatic Compounds Name: tso ds Due before lab begins. Answer in space provided. 1. Which is nitrated faster? toluene or nitrobenzene? Explain. 2. Indicate the product formed on (mono) nitration of each of the following compounds: a) Cyanobenzene (benzonitrile) b) toluene c) benzoic acid. 3. Why is methyl m-nitrobenzoate formed in this reaction instead of o- and p-? What product would you expect if methyl benzoate underwent dinitration? 4. Methyl-m-nitrobenzoate is an excellent (identification)...
5. Iron(III) ions are used as a qualitative test for phenols (aromatic compounds containing an-OH functional group). (1 point) a. What compound was used as a positive control for the Fe3+ test in this experiment? b. Did the reaction product give a positive or negative test with Fe3+ ions? Explain. 6. Acetic anhydride was used in excess in this experiment. What does this mean, and how was the excess acetic anhydride decomposed at the end of the reaction? (1 point)
Add the following questions to the final report: a) Why does the carbomethoxy group directs the reaction to positions that are meta to it? b) Why the formation of dinitrobenzaote is substantially disfavored ? c) Would you expect small amounts of the ortho and para substituted product? How would you remove them if they are formed ? d) Why does water have a retarding effect on the nitration ? e) Explain why Benzene has lower reactivity in electrophilic addition reactions...
1.) (9 points) Give structures for the following compounds: a) meta-phenylphenol b) 6-benzyl-3-heptanol e) ortho-sec-butyltoluene 2.) (9 points) Name the following compounds: 3.) (8 points) Label the following molecules as aromatic, anti-aromatic, or non-aromatic. For the ones th aren't aromatic, explain why they are either non-aromatic or anti-aromatic. 0.8 4.) (11 points) For the following electrophilic aromatic substitution reaction: Вт, FeBr; a) Which product is the major one? b) Draw a complete mechanism for the formation of the major product...
EXPERIMENT 20 CSI: SMU Part 2. Synthesis of an Ester. Esters are compounds of the form RCOOR'. They occur naturally in many plants and animals, and can be synthesized. They have a pleasant aroma usually described as "fruity of flowery". In a Fisher esterification an ester is formed from the reaction of a carboxylic acid and an alcohol with a strong acid as a catalyst. The OH contained in the carboxylic acid group 1s replaced with the alkoxy group (O-R")...
need help with the Molarity of both parts
EXPERIMENT 8: AN OXIDATION-REDUCTION TITRATION DATA SHEET 0.2M 10 m2 Concentration of original KMnO solution Volume of Original KMnO4 solution used Molarity of KNOWN HOCg04 D.ISOM Standardization of KMnO solution. Sample 3 Sample 1 Volume H2C204 11.00ML Initial buret reading (KMnO4) .00 mc Final buret reading (KMnO4) 12.00ML Volume KMnO4 12.00ml Molarity KMnO4 Average (KMnO4) Sample 2 4:00ML 12.00mL 13.5ML . SOL Determination of Unknown Solution Sample 3 Sample 1 4ml Volume...
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