Preparation of Diphenylacetylene Post-Lab Questions: de the appropriate reagent(s) and/or product(s) for the following line reactions:...
Preparation of Diphenylacetylene Post-Lab Questions: 2. Draw a stereospecific skeleti stereospecific skeletal structure for the dibrominated intermediate formed from the first step of this week's experiment (trans-stilbene reacted with PHPB). Is this intermediate chiral optically active? Explain why or why not: Pyridinium Hydrobromide Perbromide (E)-1,2-diphenylethene 3. Draw a stereospecific skeletal structure for the dibrominated intermediate formed from the reaction of cis-stilbene with PHPB (see below). Is this intermediate chiral? Is it optically active? Explain why or why not: Pyridinium Hydrobromide...
Draw the products of the following reactions. Indicate
stereochemistry where appropriate.
POST-LAB QUESTIONS 1. Draw the product(s) of the following reactions. Indicate stereochemistry wher appropriate: 1. NaBH4 a. NH2 2. H20 1. LiAlH4 b. 2. H20 CO X ama = 10.01
1. Give the structure of the product(s) for the following addition reactions. Show appropriate stereochemistry if necessary to get the full credits. (5 points) HBr 50% H2SO4 50% H20 1. BH3. THE 2. H2O2/KOH Y CHCOOH CH3COOH YY: 20120 1. O3 2. Zn/H20
Ime 1. Give the structure of the product(s) for the following addition reactions. Show appropriate stereochemistry if necessary to get the full credits. (5 points) HBr YY50% H20 50% H2SO4 50% H20 1. BH3. THE 2. H2O2/KOH YYCHCOOH CH3COOH
Part I – Reactions Draw the expected major product(s) or
required reagent(s) for each of the following reactions.
Part 1 - Reactions (20 marks) Draw the expected major product(s) or required reagent(s) for each of the following reactions. Question Answer 1. MgBr 1. CH3CN 2. H30* 2. OH HT ОН 3. Br PPh3 1. BULI 2. CH20 CI (1 mole) ОН 5. 1. LDA ? (directed aldol condensation) 2. CH3CHO 6. HO H (cat) OH ? (cyclic anhydride) . (-H20)...
Draw the major product(s) or reagents foe the following reactions.
Pay attention to stereochemistry where appropriate.
[H], NaBH3CN, ENH2 s try mansen, ents 1. Nang 2. H2 (xs), Pd NH2 1. NaNO2, HCI 2. HBF4 1. HBr, H2O2 2. Nang 3. xs LIAIHA 4. H2O
For the reactions below, provide the missing product, reactant
or reagent(s). Show the stereochemistry where appropriate.
OH ''OH racemic Os04 H202 ao COZH Zn, H30+ + CO2
Reactions of Alkenes
For the reactions below, provide the missing product, reactant
or reagent(s). Show the stereochemistry where appropriate.
2) Reactions of Alkenes For the reactions below, provide the missing product, reactant or reagent(s). Show the stereochemistry where appropriate. HINT: Use this as preparation for the Final Exam! Solve as many as you can WITHOUT referring to resources. After writing your answers, then go check them. 2.5 points each NOTE: we will take extra points off for incorrectly drawn structures....
2. Predict the major organic product(s) of the
reactions below. Assume 1 equivalent of reagent unless otherwise
stated, it's a solvent, or an oxidizing/reducing agent. Do consider
stereochemistry and regioselectivity.
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....
POST-LAB QUESTIONS: 1. Predict the product of the following reactions. If no reaction occurs write "NR" CHs CHy CH CHs CH ning 2. Which test(s) would you use to distinguish between acetophenone and 3-pentanone? Explain why to receive credit. 3. Which test(s) would you use to distinguish between benzaldehyde and propanal? Explain why to receive credit. V_02 7