Molarity of HCl = 0.2 M
Volume of HCl = 10.00 mL = 0.01 L
Moles of HCl = molarity x volume in Litres = 0.2 M X 0.01 L = 0.002 moles
Molarity of NaOH = 0.05 M
Volume of NaOH = 20 mL = 0.02 L
Moles of NaOH = molarity x volume in Litres = 0.05 M X 0.02 L = 0.001 moles
Therefore,
concentration of HCl is more than concentration of NaOH.
Hence at equivalence point, concentration of H+ is higher than concentration of OH- ions.
Then,
[H+] = [moles of HCl - moles of NaOH] / total volume (volume of HCl + NaOH)
= (0.002 moles - 0.001 moles) /(0.01 L + 0.02 L)
= 0.033 M
[H+] = 0.033 M
pH = -log[H+]
= - log [0.033]
= 1.48
pH = 1.48
Therefore,
pH of given solution = 1.48
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