Part A : pH = 0.920
Part B : pH = 1.07
Part C : pH = 2.62
Part D : pH = 3.01
Explanation
Part A : HBr is a very strong acid and dissociates completely whereas formic acid HCHO2 is a weak acid and does not dissociate completely.
Acid dissociation constant of HCHO2 = 1.8 x 10-4
We can safely assume that all H+ in solution comes from HBr
[H+] = [HBr] = 0.120 M
pH = -log[H+]
pH = -log(0.120 M)
pH = 0.920
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