Question

27511 3369.6 28586 8063 8 3029.4 29180
Trying to figure out if it is a primary or secondary amine. what is the reading for 3369cm and 3063-3029? are they both N-H stretches?
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Answer #1

Given IR spectrum shows both primary and secondary amines.

Streching frequency (cm-1) Assignment

3369 N-H strech of primary amine

(Free N-H absorption)

3069 - 3029    N-H strech of secondary amine

3201.5 overtone of HH2 bend

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