an electron may freely move on a ring with a radius r, the schrodinger equation for this problem
an electron may freely move on a ring with a radius r, the schrodinger equation for...
JO) A Pi- electron in benzene molecule may be described in quantum com make the assumption that benzene is circular. In such a case, the potential energy is constant (1.e. V =0) and Schrodinger equation for a particle of mass me constrained to move on a circle of radius a is: (-h7/8 Tma)dade - Em for 0 SOS 27. Here is the angle that describes the position of the particle (i.e. pi-electron) around the ning a) Show that the solution...
4. Estimate the transition frequency for the poryphyrin molecule from m-11 to m 12, assuming that the pi electrons can be modeled as a particle in a ring of radius 440 picometers. (C 7. The most probable distance of the electron from the nucleus in a 1ls state hydrogen atom (with wavefunction V1) can be determined by 21. A (A) solving the eigenvalue equation: Rvw rV., finding the maximum in the 1s radial distribution function by differentiation. (C) substituting vi,...
Recall that an energy eigenfunction of any central potential V (r) may be writtren as ψn`m(r, θ, φ) = Rn`(r)Y`m(θ, φ). This problem explores the behavior of ψ in the vicinity of the origin r = 0. Recall that the function u(r) = rRn`(r) satisfies the equation − ~ 2 2m d 2u dr2 + ~ 2 `(` + 1) 2mr2 + V (r) u = Eu, (1) where E is the energy eigenvalue. Note that Eq. (1) has the...
A system consists of two particles of mass mi and m2 interacting with an interaction potential V(r) that depends only on the relative distancer- Iri-r2l between the particles, where r- (ri,/i,21) and r2 22,ひ2,22 are the coordinates of the two particles in three dimensions (3D) (a) /3 pointsl Show that for such an interaction potential, the Hamiltonian of the system H- am▽ri _ 2m2 ▽22 + V(r) can be, put in the form 2M where ▽ and ▽ are the...
8.4 The Two-Dimensional Central-Force Problem The 2D harmonic oscillator is a 2D central force problem (as discussed in TZD Many physical systems involve a particle that moves under the influence of a central force; that is, a force that always points exactly toward, or away from, a force center O. In classical mechanics a famous example of a central force is the force of the sun on a planet. In atomic physics the most obvious example is the hydrogen atom,...
Consider a cylindrical capacitor like that shown in Fig. 24.6. Let d = rb − ra be the spacing between the inner and outer conductors. (a) Let the radii of the two conductors be only slightly different, so that d << ra. Show that the result derived in Example 24.4 (Section 24.1) for the capacitance of a cylindrical capacitor then reduces to Eq. (24.2), the equation for the capacitance of a parallel-plate capacitor, with A being the surface area of...