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1. Draw the structure of the principal organic product and predict the stereochemistry...
1. Draw the structure of the principal organic product and predict the stereochemistry to be expected...
1. Draw the structure of the principal organic product and predict the stereochemistry to be expected from the reaction of (IR, 2R)-/-bromo-2-methylcyclohexane with each of the following: a. NaOCH, in CH,OH at 60° d. NaNH, in NH, dt 50° b. aqueous CH OH at 140° e. aqueous CH.CH,OH at 25° c. Nal in DMSO at 40° 2. Draw the major product(s) (showing appropriate stereochemistry when necessary) for the following reactions. Indicate the mechanism(s) in operation (SNI,SN2, El. or E2). CH,...
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate...
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate the mechanism (S, S,2, El, E2). 80°C a 2-chloro-2-methylbutane NaOH Н.о b. (R)-2-chloropentane Nac c-H DMSO с1 (снс. Cн, CH,ОН d. trans-1-chloro-3-methylcyclohexane+ NaOC(CH) e. 2-chloro-3-phenylbutane Н.о f. trans-1-bromo-3-methyleyclopentane Nal acetone NaOCH THон g 2-chloro-2-methylbutane EIOH h R-3-bromo-2-methylpentane . trans-1-bromo-2-isopropyleyclohexane CHCOK NaSH Н,о j. 1-bromopropaе NaOCH снон CH коссH). I-bromobutane m. cis-1-chloro-3-methyleyclobutane Nal DMSO сHсH,он n. (R)-2-iodo-2-phenylethane NaOH o. 1-iodobutane p. 2-bromo-3-methylbutane KOC(CH). но (S)-3-chlorocyclopentene...
describe each as Sn1, Sn2, E1 and E2 then draw a curved arrow mechanism for each reaction. NaSH DMSO SH KOH HO DMSO...
describe each as Sn1, Sn2, E1 and E2 then draw a
curved arrow mechanism for each reaction.
NaSH DMSO SH KOH HO DMSO Br NANH NH3 OTs NH TsO TsO CHs CH3 Nal CH3 acetone CH O O
answer all 1. In each of the following, indicate which S2 reaction will occur faster. Explain...
answer all
1. In each of the following, indicate which S2 reaction will occur faster. Explain your reasoning. a. 1-bromo-2,2-dimethylpropane or 1-bromo-3-methylbutane with Nal in DMSO. b. 1-iodopentane with NaN, in ethanol or NaSCH, in ethanol, c. Reaction of isobutyl iodide with NaBr in acetone or in ethanol. 2. In each of the following, indicate which S, 1 reaction will occur faster. Explain your reasoning. a. Reaction of I-chloro-1-methylcyclohexane or 1-chloro-2-methylcyclohexane in aqueous ethanol. b. Reaction of 2-chloropentane or 3-bromohexane...
please explain why and how they are E2/SN2/SN1/E1 3. Draw a structural formula for the major organic product(s) of e...
please explain why and how they are E2/SN2/SN1/E1
3. Draw a structural formula for the major organic product(s) of each reaction and specify the mechanism by which each product is formed (SNI, S2, El, or E2). • NaOH H20 CH,CH ON CH,CH OH CH ON CH,OH CH OH Na DMSO
1. Determine whether the following reactions will go through SN1, SN2, E1, or E2 mechanism a....
1. Determine whether the following reactions will go through SN1, SN2, E1, or E2 mechanism a. 1-bromobutane + sodium hydroxide b. 2-chloro-2-methylpentane + sodium hydroxide + heat C. 2,3-dimethyl-3-bromopentane + water d. 2-bromobutane + methanol 2. Draw the major product for the following reactions (draw both products if racemic): NaSH DMSO TsO CHA Nal CH, acetone CH,CH,ONa+ ethanol CH,OH/H-0 Solite Nal (1 equiv.) acetone F CH2CH OH 25°C
3. For each reaction, draw the structure of the major product(s) including stereochemistry where appropriate. Fill n t...
3. For each reaction, draw the structure of the major product(s) including stereochemistry where appropriate. Fill n the box below each arrow with the mechanism(s) that will be followed (SN1/E1, SN2, or E2). For SN1/E1 reactions, draw products for both. NaCN DMF tBuOH 言言言 MeOH * | CH30 CH OH DMSO R-2-bromopentane
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate...
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate stereochemistry when appropriate. C(CH3)3 NASH Br (S)-2-bromononane - acetonitrile KOH CH,OH NaCN HE Br Acetonitrile C2H5 H, Br NaOH Acetone excess HBr ROOR HC1 + Br Na o DMSO
3. Draw a structural formula for the major organic product(s) of each reaction and specify the...
3. Draw a structural formula for the major organic product(s) of each reaction and specify the mechanism by which each product is formed (Syl, SN2, E1, or E2). NaOH HO CH3CH2ON CH3CH2OH CH ON CH OH Br CH,OH Na DMSO
1. Draw the structure of the principal organic product and predict the stereochemistry to be expected from the reaction of (IR, 2R)-/-bromo-2-methylcyclohexane with each of the following: a. NaOCH, in CH,OH at 60° d. NaNH, in NH, dt 50° b. aqueous CH OH at 140° e. aqueous CH.CH,OH at 25° c. Nal in DMSO at 40° 2. Draw the major product(s) (showing appropriate stereochemistry when necessary) for the following reactions. Indicate the mechanism(s) in operation (SNI,SN2, El. or E2). CH,...
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate the mechanism (S, S,2, El, E2). 80°C a 2-chloro-2-methylbutane NaOH Н.о b. (R)-2-chloropentane Nac c-H DMSO с1 (снс. Cн, CH,ОН d. trans-1-chloro-3-methylcyclohexane+ NaOC(CH) e. 2-chloro-3-phenylbutane Н.о f. trans-1-bromo-3-methyleyclopentane Nal acetone NaOCH THон g 2-chloro-2-methylbutane EIOH h R-3-bromo-2-methylpentane . trans-1-bromo-2-isopropyleyclohexane CHCOK NaSH Н,о j. 1-bromopropaе NaOCH снон CH коссH). I-bromobutane m. cis-1-chloro-3-methyleyclobutane Nal DMSO сHсH,он n. (R)-2-iodo-2-phenylethane NaOH o. 1-iodobutane p. 2-bromo-3-methylbutane KOC(CH). но (S)-3-chlorocyclopentene...
describe each as Sn1, Sn2, E1 and E2 then draw a
curved arrow mechanism for each reaction.
NaSH DMSO SH KOH HO DMSO Br NANH NH3 OTs NH TsO TsO CHs CH3 Nal CH3 acetone CH O O
answer all
1. In each of the following, indicate which S2 reaction will occur faster. Explain your reasoning. a. 1-bromo-2,2-dimethylpropane or 1-bromo-3-methylbutane with Nal in DMSO. b. 1-iodopentane with NaN, in ethanol or NaSCH, in ethanol, c. Reaction of isobutyl iodide with NaBr in acetone or in ethanol. 2. In each of the following, indicate which S, 1 reaction will occur faster. Explain your reasoning. a. Reaction of I-chloro-1-methylcyclohexane or 1-chloro-2-methylcyclohexane in aqueous ethanol. b. Reaction of 2-chloropentane or 3-bromohexane...
please explain why and how they are E2/SN2/SN1/E1
3. Draw a structural formula for the major organic product(s) of each reaction and specify the mechanism by which each product is formed (SNI, S2, El, or E2). • NaOH H20 CH,CH ON CH,CH OH CH ON CH,OH CH OH Na DMSO
1. Determine whether the following reactions will go through SN1, SN2, E1, or E2 mechanism a. 1-bromobutane + sodium hydroxide b. 2-chloro-2-methylpentane + sodium hydroxide + heat C. 2,3-dimethyl-3-bromopentane + water d. 2-bromobutane + methanol 2. Draw the major product for the following reactions (draw both products if racemic): NaSH DMSO TsO CHA Nal CH, acetone CH,CH,ONa+ ethanol CH,OH/H-0 Solite Nal (1 equiv.) acetone F CH2CH OH 25°C
3. For each reaction, draw the structure of the major product(s) including stereochemistry where appropriate. Fill n the box below each arrow with the mechanism(s) that will be followed (SN1/E1, SN2, or E2). For SN1/E1 reactions, draw products for both. NaCN DMF tBuOH 言言言 MeOH * | CH30 CH OH DMSO R-2-bromopentane
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate stereochemistry when appropriate. C(CH3)3 NASH Br (S)-2-bromononane - acetonitrile KOH CH,OH NaCN HE Br Acetonitrile C2H5 H, Br NaOH Acetone excess HBr ROOR HC1 + Br Na o DMSO
3. Draw a structural formula for the major organic product(s) of each reaction and specify the mechanism by which each product is formed (Syl, SN2, E1, or E2). NaOH HO CH3CH2ON CH3CH2OH CH ON CH OH Br CH,OH Na DMSO
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