Worksheet: Kinetics and Rate Order 1. The rate of the reaction NO, + CO → NO...
in investigation is performed in which the concentration of nitrogen dioxide reacting is measured as a function of time. Time (S) [NO2](mol/L) 0.500 0.445 0.380 0.340 0.250 0.175 12 30 90 180 a) Plot a graph of (NO) vs. time (5 marks) b) Determine the average rate of reaction of NO2 between 10 and 60s (2 marks) c) As the [NO2) halved, what was the effect on the instantaneous rate of reaction? (2 marks)
1. The kinetics of the following reaction have been studied: N2 + 3 H2 → 2 NH3 The rate of of appearance of NH3 was measured as ∆[NH3]/∆t = 9.00 x 10-2 mol L-1 s-1 (a) What is the rate of the reaction in mol L-1 s-1? (b) What is ∆[N2]/∆t in mol L-1 s-1? (c) What is ∆[H2]/∆t in mol L-1 s-1? 2. The initial rate of the reaction of species A and B A + 2 B →...
1. Initial‑rate data at a certain temperature is given in the table for the reaction N2O3(g)⟶NO(g)+NO2(g) [N2O3]0(M) Initial rate (M/s) 0.100 0.510 0.200 1.020 0.300 1.530 Determine the value and units of the rate constant. k= units: 2. Using the data in the table, determine the rate constant of the reaction and select the appropriate units. A+2B⟶C+D Trial [A] (M)[A] (M) [B] (M)[B] (M) Rate (M/s) 1 0.340 0.340 0.0127 2 0.340 0.680 0.0127 3 0.680 0.340 0.0508 k= Units...
The decomposition of dinitrogen tetroxide to nitrogen dioxide at 400°C follows first-order kinetics with a rate constant of 9.17 ×10-3 s-1. Starting with pure N2O4, how many minutes will it take for 85.0% to decompose?
1) 2) 3) The decomposition of dinitrogen tetroxide to nitrogen dioxide at 400°C follows first-order kinetics with a rate constant of 3.84 X10-3-1. Starting with pure N204, how many minutes will it take for 38.0% to decompose? Suppose the surface-catalyzed hydrogenation reaction of an unsaturated hydrocarbon has a rate constant of 0.374 M/min. The reaction is observed to follow zero-order kinetics. If the initial concentration of the hydrocarbon is 2.90 M, what is the half-life of the reaction in seconds?...
1) Hydrogen peroxide, H2O2(aq), decomposes to H2O(l) and O2(g) in a reaction that is first order in H2O2 and has a rate constant k = 1.06×10−3 min−1 at a given temperature. How long will it take for 15% of a sample of H2O2 to decompose? 2)The decomposition of nitrogen dioxide, NO2, into nitrogen monoxide and oxygen at a high temperature is second-order in NO2. The rate constant for this reaction is 3.40 L/mol×min. Determine the time needed for the concentration...
1. A reaction was shown to follow second-order kinetics. How much time is required for [A] to change from 0.500 M to 0.160 M? (k = 0.456 M⁻¹ s⁻¹) 2. A substance decomposes with a rate constant of 9.05 × 10⁻⁴ s⁻¹. How long does it take for 16.0% of the substance to decompose? 3. How long will it take for the concentration of A to decrease from 0.500 M to 0.100 M in the first-order reaction A → B?...
The rate constant for this first‑order reaction is 0.500 s−1 at 400 degrees C. A⟶products How long, in seconds, would it take for the concentration of A to decrease from 0.990 M to 0.340 M?
2. Using the data in the table, determine the rate constant of the reaction and select the appropriate units. A+2B⟶C+D Trial [A] (M)[A] (M) [B] (M)[B] (M) Rate (M/s) 1 0.340 0.340 0.0127 2 0.340 0.680 0.0127 3 0.680 0.340 0.0508 k= Units 3. The rate constant for this first‑order reaction is 0.480 s−1 at 400 ∘C. A⟶products How long, in seconds, would it take for the concentration of A to decrease from 0.650 M to 0.270 M? 4. After...
At elevated temperatures, nitrogen dioxide decomposes to nitrogen oxide and oxygen: The reaction is second order in NO2 with a rate constant of 0.543 M-1 s-1 at 300°C If the initial [NO2] is 0.260 M it will take ________ seconds for the concentration to drop to 0.100 M. 11.3 8.8 × 10-2 -0.611 3.34 0.299