In this reaction first one ketone group is protected with 1,2-diol which gives a 1,3-dioxolane. Then the ester group is reduced to corresponding alcohol and methanol. Then work up with Water which gives 1,3- dioxolane to ketone.
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Provide Products i Include sterochemistry and /or stereoisomers. Provide MAJOR product if many products. "OH + PBrz Na Bhu CH3 CH₃OH
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Provde Products Indude sleochomistry and lar stereois0mers. Provide MATOR paduct if many prodlucts. PBrs OH + Na BHy B ? CH3OH CH3
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Propose a mechanism that can account for the following rearrangement. Use proper curved arrow notation. Show ALL STEPS & intermediates. a Br CH₂ Mg Bra Etzo
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[1] Draw the chemical structure of the reagents and products to prepare compound (A) starting from Benzene. This is a multistep preparation. COOH O- - - SOZH Compound (A) [2] Identify the absolute configuration of the chiral carbon atom (with an asterisk) if it is [R] or (S). Show the priorities and rotation. (The atomic numbers are H=1, C=6, N=7, O=8, CI=17] HO...
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The Mole (1.5 pt) If you plan to dissolve 0.075 moles of sucrose (C12H22011) to make 150 mL of solution... > (a) How many grams of sucrose should you plan to measure out? (b) What is the molarity of the resulting solution?
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Problem 1: Projectile motion Famous American football player Cam Newton throws a football at a speed of 27 ms -- and at an angle of 10° above the horizontal. He releases it at a height of 2 m above the ground. A defender 12 m away jumps to intercept the ball. If the defender can reach to 3.5 m above the ground are they able to intercept the...
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Identifying Chemical Reactions (2 pts) Pro ho fan cost can Name the organic reaction happening at each of the following steps in the Krebs cycle (pictured at right): (a) succinate → fumarate waloncette Malate (b) fumarate → malate Fumarate Pumarte o a-ketoglutarala Succinyl-CoA Succinate (c) malate → oxaloacetate (d) isocitrate → a-ketoglutarate* (two rxns!!)
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Calculate the magnetic field due to (i) a very thin current sheet in the xy-plane (infinitely sized in x, y) with a...
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1. (6 points) Let f(x) = -x2 - 2x + 3. (a) Does the graph of f(x) open upward or downward? Justify your answer. 6) Algebraically find the vertex and axis of symmetry of f(x). Report each answer as an ordered pair and equation, respectively, Vertex Axis of Symmetry: (C) Algebraically find the X- and y-intercepts of f(x). Report your answer(s) as an ordered pair(s). x-intercepts: y-intercept: (a) Using parts...
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Intermolecular Forces and Boiling Point (3 pts) Formaldehyde (CH2O) appeared in your exam. (a) Use Lewis structures to show a molecule of formaldehyde forming hydrogen bonding attractions with a molecule of water. CLEARLY identify the donor and acceptor in this drawing. (b) Referring to your drawing above, briefly explain why two formaldehyde molecules can't form hydrogen bonding attractions between each other. (c) Formaldehyde molecules are twice...