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The following reaction has a small, positive AG and takes place slowly at room temperature: 4....
The following reaction has a small, positive AG and takes place slowly at room temperature: 4....
The following reaction has a small, positive AG and takes place slowly at room temperature: 4. H-OH H3C-OH H-CI H3C-CI (a) The mechanism for the reaction is shown below. Which bond is being broken in the slowest step? Which bond is being made? slow Hас -он; Н-Он +CI Step 1 H3C-CI endothermic fast Н-СI Hас -он +CI + Step 2 HaC-он exothermic (b) Based on this multi-step mechanism, draw a free energy reaction coordinate diagram for the reaction. Draw in...
4. The following reaction has a small, positive AG and takes place slowly at room temper H3C-Cl + H-OH - H3C-OH + H...
4. The following reaction has a small, positive AG and takes place slowly at room temper H3C-Cl + H-OH - H3C-OH + H-CI (a) The mechanism for the reaction is shown below. Which bond is being broken in the sky step? Which bond is being made? slow Step 1 H3C-Cl + H-OH- - H3C-CH3 + CI endothermic fast Step 2 H3C-OH3 + 1 - H2C-Cl + H-CI exothermic (b) Based on this multi-step mechanism, draw a free energy reaction coordinate...
3. Indicate the nucleophilic group and the electrophilic group in each of the following reactions, then draw curved...
3. Indicate the nucleophilic group and the electrophilic group in each of the following reactions, then draw curved arrows to show the electron flow: (a) H- N H -CH: (D) - (C) NH :CI: CI-APë: :CA: 1-ci: A-CI: 4. The following reaction has a small, positive AG and takes place slowly at room temperature: H3C-CI H-OH - H3C-OH - H-CI (a) The mechanism for the reaction is shown below. Which bond is being broken in the slowest step? Which bond...
6. Which of the following statements is not true? A) Bond breaking is endothermic. B) The...
6. Which of the following statements is not true? A) Bond breaking is endothermic. B) The bond dissociation energy for bond breaking is always negative. C) Bond making is exothermic. D) The bond dissociation energy for bond formation is always negative. 37. Using the bond dissociation energies given, calculate AH® for the following reaction. CH,CH -Br + H2O CH,CH-OH + HBr AH KJ/mol Bond A-B CH3CH2-Br H-OH сHCH-он H-Br A) +108 KJ/mol B) -130 KJ/mol C) -22 KJ/mol D) +22...
2). Consider the following intramolecular S2 reaction. no ♡ + HI A) (5 pts) Use the...
2). Consider the following intramolecular S2 reaction. no ♡ + HI A) (5 pts) Use the table of Bond Dissociation Enthalpies (at the back of the exam) to calculate the approximate ΔΗπη. B) (3 pts) Is the reaction endothermic or exothermic? Why? C) (6 pts) Draw the Reaction Energy Coordinate Diagram. Label the axes, reactant(s), product(s), transition state(s), intermediate(s), activation energy, and reaction enthalpy. D) (3 pts) In regards to entropy, would you expect the reaction to be favorable, or...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23,...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
1) Write a Reaction equation using 4- aminobenzenesulfulfonic acid (aniline derivative) and 8-ani...
1) Write a Reaction equation using 4- aminobenzenesulfulfonic
acid (aniline derivative) and 8-anilino-1-naphthalenesulfonic acid
(coupling agent). Write the mechanism.
SYNTHESIS OF AZO DYES INTRODUCTION Humans' love of color dates back almost to prehistoric times, yet it is not actually until the modern era that the full range of the rainbow has been accessible to the majority of people irn their clothes and other textiles. Ancient or medieval times have often been described as being quite splendid with their "tyrian purple"...
The following reaction has a small, positive AG and takes place slowly at room temperature: 4. H-OH H3C-OH H-CI H3C-CI (a) The mechanism for the reaction is shown below. Which bond is being broken in the slowest step? Which bond is being made? slow Hас -он; Н-Он +CI Step 1 H3C-CI endothermic fast Н-СI Hас -он +CI + Step 2 HaC-он exothermic (b) Based on this multi-step mechanism, draw a free energy reaction coordinate diagram for the reaction. Draw in...
4. The following reaction has a small, positive AG and takes place slowly at room temper H3C-Cl + H-OH - H3C-OH + H-CI (a) The mechanism for the reaction is shown below. Which bond is being broken in the sky step? Which bond is being made? slow Step 1 H3C-Cl + H-OH- - H3C-CH3 + CI endothermic fast Step 2 H3C-OH3 + 1 - H2C-Cl + H-CI exothermic (b) Based on this multi-step mechanism, draw a free energy reaction coordinate...
3. Indicate the nucleophilic group and the electrophilic group in each of the following reactions, then draw curved arrows to show the electron flow: (a) H- N H -CH: (D) - (C) NH :CI: CI-APë: :CA: 1-ci: A-CI: 4. The following reaction has a small, positive AG and takes place slowly at room temperature: H3C-CI H-OH - H3C-OH - H-CI (a) The mechanism for the reaction is shown below. Which bond is being broken in the slowest step? Which bond...
6. Which of the following statements is not true? A) Bond breaking is endothermic. B) The bond dissociation energy for bond breaking is always negative. C) Bond making is exothermic. D) The bond dissociation energy for bond formation is always negative. 37. Using the bond dissociation energies given, calculate AH® for the following reaction. CH,CH -Br + H2O CH,CH-OH + HBr AH KJ/mol Bond A-B CH3CH2-Br H-OH сHCH-он H-Br A) +108 KJ/mol B) -130 KJ/mol C) -22 KJ/mol D) +22...
2). Consider the following intramolecular S2 reaction. no ♡ + HI A) (5 pts) Use the table of Bond Dissociation Enthalpies (at the back of the exam) to calculate the approximate ΔΗπη. B) (3 pts) Is the reaction endothermic or exothermic? Why? C) (6 pts) Draw the Reaction Energy Coordinate Diagram. Label the axes, reactant(s), product(s), transition state(s), intermediate(s), activation energy, and reaction enthalpy. D) (3 pts) In regards to entropy, would you expect the reaction to be favorable, or...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
1) Write a Reaction equation using 4- aminobenzenesulfulfonic
acid (aniline derivative) and 8-anilino-1-naphthalenesulfonic acid
(coupling agent). Write the mechanism.
SYNTHESIS OF AZO DYES INTRODUCTION Humans' love of color dates back almost to prehistoric times, yet it is not actually until the modern era that the full range of the rainbow has been accessible to the majority of people irn their clothes and other textiles. Ancient or medieval times have often been described as being quite splendid with their "tyrian purple"...
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