When a 2.00g (0.0200 mol) KHCO3 was mixed with 30.0 mL of approximately 2M HCl, the temperature fall by 3.7oC
Calculate the enthalpy change of this reaction per mole of KHCO3.
Solution-
The equation can be written as
K2CO3 + 2HCl → 2KCl + H2O + CO2
As we know that
Q = msΔT
we know that
Mass = Volume*Density
Putting the values in the equation
= 30ml*1.00g/ml
= 30g
Given
Mass = 30g
Specific heat of mixture = 4.184 J/goC
ΔT = 3.70C
substute these value we get
Q = (30g)(4.184J/goC)(3.70C)
= 464.424 J
This is for 0.02 mol of K2CO3 .
The amount of heat liberated per one mole of K2CO3= 464.424 J * 1
mol / 0.02 mol
= 23221.2J
As the temperature of mixture falls it indicates that the heat is
decrease, Therefore the ΔH must have +vesign.
=>ΔH = 23221.2 J
When a 2.00g (0.0200 mol) KHCO3 was mixed with 30.0 mL of approximately 2M HCl, the...
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When a 2.76g (0.0200 mol) K2CO3 was mixed with 30.0 mL of approximately 2M HCl, the temperature rose by 5.2oC Calculate the enthalpy change of this reaction per mole of K2CO3. Assume that the specific heat of tyhe final mixture is 4.184 J/goC and that its density is 1.00g/mL Please explain how do you do the enthalpy change part and how do you use the formula to find the change.
skip (a): the balancing part!
just solve (b)
2. When 2.76 g (0.0200 mol) of K,CO, was mixed with 30.0 ml of approximately 2M HCI, the temperature rose by 5.2 °C. (a) Write a balanced equation for this reaction. (b) Calculate the enthalpy change (AH) of this reaction per mole of potassium carbonate. Assume that the specific heat of the final mixture is 4.184 J/gºC, and that its density is 1.00 g/mL.
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