• Explain why the halogens are orthopars dilectons but are deactivators 1. Draw the mechanism of...
Objectives - Section 1 • Identify a substituent as an ortho para director or a meta director, Draw the resonance structure that explains the relative directing ability of a specific substituent. Classify a substituent as an activating or a deactivating group. Explain why the halogens are ortho/para directors but are deactivators. • 1. Draw the mechanism of the reaction below and use resonance structures of the arenium ion intermediate to explain why the starting material is an ortho/para director
3. Draw all possible resonance structures for aniline. Relate the resonance structures to why it is an ortho/para director. 3. Drawhy it is нони 19 Pa
#1. Using curved arrows to symbolize electrons, write a complete reaction mechanism for the bromination of acetanilide to create the product. Include the resonance structures for any charged, delocalized intermediates that are involved. #2. Why does performing the experiment at 0 degrees Celsius help you identify some of the relative rates of reactivity? #3. Explain why a methyl group is a mildly activating group while a methoxy group is strong activating. #4. Explain why-- NH2 act as an activator and--...
Using resonance structures and a brief explanation, explain why phenol (C6H5OH) is an ortho-para director (25 pts).
Methoxy benzene (anisole) reacts with a mixture of FeBr3 and Br2 and the major products obtained are ortho- and para-substituted. Draw the 3 major and minor products of the reaction and use resonance structures of the carbocation intermediate to explain why ortho and para substitution occur in preference to the meta-substitution.
2. Using resonance contributors for the intermediate carbocation, explain why a phenyl group is an ortho-para director. FeCl3 + Cl2
(V) 10pts. When aniline (C6H3-NH2) reacts with bromonium ion (NO2. the nitro group can become bonded to a carbon at one of the three possible positions: ortho, meta, and para to the -NH2 group in the benzene ring. Consider meta and ortho attack and draw RESONANCE STRUCTURES for the carbocations that result when NO2 undergoes electrophilic aromatic substitution to aniline. Then, on the basis of these resonance structures, explain whether the --NH2, group.is meta director, or ortho/para director. Show which...
director in an EAS reaction . Use the structures Of all of its resonance contributors to support 2. Explain why anisole is an ortho-/para- in your written your answer Refer to structures explanation. 20 20 CH₃ 6/20
3. Mechanism: Draw the curved arrow mechanism for the following hydrolysis reaction, only draw the mechanism from the starting material to the neutral functional group intermediate. Additionally, indicate what is in the final product by writing Y="appropriate atom here". Use only the reagents provided below, in your mechanism. (5 pts) excess NaOH H2O, heat HNĐ neutral functional group intermediate 9. Mechanism: Draw the curved arrow mechanism for the following reaction. Please be aware that during the mechanism you will form...
In nitration of acetanilide(synthesis of p-nitroaniline) main product is ortho and para. Explain why ortho and para product is major in resonance and mechanism term.