Homework Answers
First reaction with Br2/H2O is an example for Electrophilic Addition mechanism then with NaOH gives Cyclic ether by SN2 reaction.
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( Using arrows provide a mechanistic explanation of the course of the reaction (Z)-3-methylpent-2-ene and bromine...
1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of...
1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism); (ii) write the product/s of the reaction; (iii) name the reaction product/s. (4 x 5= 20 points) a. Sulfuric acid catalyzed hydration (addition of H:0) of 2-methyl-but-2-ene b. Addition of molecular bromine to l-methyl-cyclohex-l-ene c. Addition of hydrogen bromide to (3R)-2,3-dimethyl-pent-1-ene, present product/s through Fischer projection. d. Hydroboration...
In each of the following nucleophilic addition reactions (i) using arrows provide a mechanistic explanation of...
In each of the following nucleophilic addition reactions (i) using arrows provide a mechanistic explanation of the course of the reaction (show intermediates); (ii) write the product of the reaction. (32 points) a. Show mechanism of acetal formation through hemiacetal reacting acetone with (1R,2S)- cyclopentan-1,2-diol under acidic catalysis. The actal formation reaction from hemiacetal is intramolecular reaction. (6 points = 3 points for hemiacetal + 3 points for acetal)
CM-241 F19 Homework # 7 is due on 11/8/19 at 5 pon in the mail box...
CM-241 F19 Homework # 7 is due on 11/8/19 at 5 pon in the mail box labeled CM-241 near room SC236 Supplementary session is on 10/31/19 between 5:30 pm - 7:30 pm in the room 194CAMP 1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism): (ii) write the products of the reaction; (iii) name the reaction product/s....
Help with explanation of 2, 3 and 4 please?? I. Provide a curved-arrow mechanism for the first step of the reductio...
Help with explanation of 2, 3 and 4 please??
I. Provide a curved-arrow mechanism for the first step of the reduction of vanillin with borohydride in methanol. Show and explain the role of the protic solvent in the reaction (10%) 2. Balance the reaction of vanillin with sodium bordride shown below (assuming alth borohydride reacts with the cyclohexanone as shown) and the subsequent hydrolysis under acidic conditions. (15%) RH. CON CHR 3. Because NaBes a mild reducing agent, it must...
1-24 need help really lost Proton Transfer: deprotonation D. 1) Add the appropriate curved arrows for...
1-24 need help really lost
Proton Transfer: deprotonation D. 1) Add the appropriate curved arrows for the following deprotonation step. Also add the other product notice how the Tema s can be converted to this by use of a strong base such as sodium a sodium ion (Na) is not drawn, in this case it is just a spectatorio PCW27 - Mechanistic steps - Part Name: Time spent 2) Label the above compounds with the appropriate name from the previous...
Titration: Acids and Bases 2. How can you determine which acid is diprotic? 3. using the...
Titration: Acids and Bases
2. How can you determine which acid is diprotic?
3. using the answers to questions one and two, which acid is
diprotic?
4. Which base has more hydroxide ions per molecule?
Acid Volume Base Base Initial Volume (mL) Base Final Volume (mL) Volume of Base Used (mL) Acid: Base Ratio Acid 1 20 mL Base 1 50 mL 34.5 15.5 4:3 Acid 2 20 mL Base 1 Acid 1 20 mL Base 2 Acid 2 20...
1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism); (ii) write the product/s of the reaction; (iii) name the reaction product/s. (4 x 5= 20 points) a. Sulfuric acid catalyzed hydration (addition of H:0) of 2-methyl-but-2-ene b. Addition of molecular bromine to l-methyl-cyclohex-l-ene c. Addition of hydrogen bromide to (3R)-2,3-dimethyl-pent-1-ene, present product/s through Fischer projection. d. Hydroboration...
CM-241 F19 Homework # 7 is due on 11/8/19 at 5 pon in the mail box labeled CM-241 near room SC236 Supplementary session is on 10/31/19 between 5:30 pm - 7:30 pm in the room 194CAMP 1. In each of the following addition reactions (1) using arrows provide a mechanistic explanation of the course of the reaction (show transition state for concerted mechanism and intermediate for two-step mechanism): (ii) write the products of the reaction; (iii) name the reaction product/s....
Help with explanation of 2, 3 and 4 please??
I. Provide a curved-arrow mechanism for the first step of the reduction of vanillin with borohydride in methanol. Show and explain the role of the protic solvent in the reaction (10%) 2. Balance the reaction of vanillin with sodium bordride shown below (assuming alth borohydride reacts with the cyclohexanone as shown) and the subsequent hydrolysis under acidic conditions. (15%) RH. CON CHR 3. Because NaBes a mild reducing agent, it must...
1-24 need help really lost
Proton Transfer: deprotonation D. 1) Add the appropriate curved arrows for the following deprotonation step. Also add the other product notice how the Tema s can be converted to this by use of a strong base such as sodium a sodium ion (Na) is not drawn, in this case it is just a spectatorio PCW27 - Mechanistic steps - Part Name: Time spent 2) Label the above compounds with the appropriate name from the previous...
Titration: Acids and Bases
2. How can you determine which acid is diprotic?
3. using the answers to questions one and two, which acid is
diprotic?
4. Which base has more hydroxide ions per molecule?
Acid Volume Base Base Initial Volume (mL) Base Final Volume (mL) Volume of Base Used (mL) Acid: Base Ratio Acid 1 20 mL Base 1 50 mL 34.5 15.5 4:3 Acid 2 20 mL Base 1 Acid 1 20 mL Base 2 Acid 2 20...
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