437 Predict whether the following substituents on the benzene ring are likely to be ha para...
10. (12 points) Cua CHaCHa Les eb Predict whether the following substituents on the benzene ring are likely to be ortho/para directing or meta directing and whether they are likely to be ring activating or ring deactivating ..n(CH3)2 CEN ОСН з -NO C-OCH 11. (6 points) Starting with benzene as the only aromatic starting material, devise a
An NH2 substituent in an aromatic ring is: Select one: a. activating ortho-, meta- and para-directing b. deactivating and ortho- and para-directing c. deactivating and meta-directing d. activating and meta-directing e. activating and ortho- and para-directing
Label the following as activating (A) or deactivating (D), and then also as ortho/para directors (OP) or meta directors (M). Write the answer below each group. N "Here with other ty A/D? = = = = OP/M? = f) Using resonance structures, explain why a nitro group is "meta-directing" (i.e. does the nitro group actually affect the meta positions?) g) As mentioned in class, the halogens are a bit anomalous as substituents on the aromatic ring: they are deactivating groups,...
3. Draw the structural formulas for the following compounds. (10 points, 2 each) a. 2-propanol b. 2-methyl-5-hexene-2-ol c. 3-cyclohexenol d. 4-nitrophenol e. phenol 4. Classify the following substituents as ortho/para or meta directing and activating or deactivating (two part answer for each group) (note the line 34 indicates where the group is attached to the benzene ring. (12points, 2 each) NH2 Ooh &r HC-CH₃ No? QH
1. Complete the following exercises: A. Indicate whether each substituted benzene ring will produce predominantly ortho/para or meta products) after electrophilic aromatic substitution: B. Identify the molecule that can undergo nucleophilic aromatic substitution by addition/elimination: