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3. Draw the structural formulas for the following compounds. (10 points, 2 each) a. 2-propanol b....
10. (12 points) Cua CHaCHa Les eb Predict whether the following substituents on the benzene ring...
10. (12 points) Cua CHaCHa Les eb Predict whether the following substituents on the benzene ring are likely to be ortho/para directing or meta directing and whether they are likely to be ring activating or ring deactivating ..n(CH3)2 CEN ОСН з -NO C-OCH 11. (6 points) Starting with benzene as the only aromatic starting material, devise a
437 Predict whether the following substituents on the benzene ring are likely to be ha para...
437 Predict whether the following substituents on the benzene ring are likely to be ha para directing or meta directing and whether they are like to be ring activating or ring deactivating deact vabang a) - NH(CH 4.38 For each of the monosabstituted benenes shown below, (1) Indicate whether the substituent is ortho, para directing or meta directing (2) Draw the structure of the main monosubstitution product for each of the reactions indicated orth. OCH3 + HCl -OCHE (fecutulys ortho...
Label the following as activating (A) or deactivating (D), and then also as ortho/para directors (OP)...
Label the following as activating (A) or deactivating (D), and then also as ortho/para directors (OP) or meta directors (M). Write the answer below each group. N "Here with other ty A/D? = = = = OP/M? = f) Using resonance structures, explain why a nitro group is "meta-directing" (i.e. does the nitro group actually affect the meta positions?) g) As mentioned in class, the halogens are a bit anomalous as substituents on the aromatic ring: they are deactivating groups,...
1. please check what is wrong. Thank you! Determine the product formed when each compound is treated with...
1. please check what is wrong. Thank you!
Determine the product formed when each compound is treated with Br2 and FeBr3. Drag the atom labels to their appropriate positions. CN Atom labels H H Br Br2 A. FeBr Br H OH OH Br Br. Br2 FeBr3 H H Br Br H Br2 FeBr H1 H Reset T Rank the compounds in each group in order of decreasing reactivity in electrophilic aromatic substitution. CI Decreasing reactivity Rank the compounds in each...
THESE ARE THE 6 reagents 1) 1-naphthol 2) 4-bromophenol 3)phenol 4) anisol 5) acetanilide 6) diphenyl...
THESE ARE THE 6 reagents
1) 1-naphthol
2) 4-bromophenol
3)phenol
4) anisol
5) acetanilide
6) diphenyl ether
rates of electrophilic aromatic substitution lab using bromine. 1. (3 pts.) Draw the structures of all six reactant arenes that will be used in this lab 2. (6 pts.) Beneath each structure you have a. If the substituent is ring b. If the electrophile will be drawn in question 1, note the following: activating or deactivating directed to an ortho, meta, and/or para...
1.The best way to describe the "arrow" showing the mechanism of EAS is: A.it goes from...
1.The best way to describe the "arrow" showing the mechanism of EAS is: A.it goes from the attacking atom (electrophile) to the carbon being attacked. B.it goes from the attacking atom to the new bond being formed. C.it goes from the electron pair in the pi-bond on the ring to the new sigma bond being formed. D.it involves a half-head arrow from the attacking species and a half-head arrow from the pibond to the new sigma bond to be formed....
Question 3 1s 3 ORTHO Today we learned about adding a second group to a mono-substituted...
Question 3
1s 3 ORTHO Today we learned about adding a second group to a mono-substituted benzene ring. Any group on a benzene will affect the rate of the reaction (activated or deactivated relative to benzene) and the regioselectivity Where does the electrophile add? Ortho? Meta? Para? Some combination thereof? We found that EDGs (electron-donating groups) direct the electrophile to the ortho and para positions while EWGs (electron-withdrawing groups) direct the electrophile to the meta position. Now, it is time...
on T. Maitiple choiee. Select the best anaver. (0.5 points each) i. Which statement below is...
on T. Maitiple choiee. Select the best anaver. (0.5 points each) i. Which statement below is true the aromatic substitution involving the bromina of benzene? znBry acts as the Lewis acid B) Feßr, acts as the Lewis base c) Br, acts as nugaed aromatic ring D) n-electrons of benzene act as the electrophile E) FeBr, acta as the Lewis acid. a what is rue about the rate and the najor predust of nitration of the methoxybenzene? A) Proceeds more rapidly...
2. D type and strength of each substituents as activating(A) or outcome as ortho-para (O/P) or...
2. D type and strength of each substituents as activating(A) or outcome as ortho-para (O/P) or meta(M) directors. (6 pts) you expect an electrophile to be attached to the ring You must identify the deactivating(D) and also the expected regiochemical 3. Use aromatic, non aromatic or antiaromatic concepts to explain the reactions or molecules shown (6 pts) Provide a curved arrow mechanism to show the formation of a aromatic carbocation intermediate Show the final product H-I The pK,values for the...
Lumili alle for the following compound? - (CH)CHCH.COCH,CH, a. 2-methyl-4-hexanone c. 2-methyl-3-hexanone b. 5-methyl-3-hexanone d. ethyl...
Lumili alle for the following compound? - (CH)CHCH.COCH,CH, a. 2-methyl-4-hexanone c. 2-methyl-3-hexanone b. 5-methyl-3-hexanone d. ethyl isopropyl ketonel. 25-Identify the directing effect of the ring substituent in the following reaction: BO, HBO. (a) o.p., activating (b) m-, deactivating (c) o.p., deactivating (d) None of these 26--Ketones are easily reduced to CH3-C-CH3 a-Secondary alcohol b- Primary alcohol c- to acetaldehyde d- to carboxylic acid 27-. What is the structure of the azo group? a-N- b-N-N- C-NEN- d-NEN- 28-What class of organic...
10. (12 points) Cua CHaCHa Les eb Predict whether the following substituents on the benzene ring are likely to be ortho/para directing or meta directing and whether they are likely to be ring activating or ring deactivating ..n(CH3)2 CEN ОСН з -NO C-OCH 11. (6 points) Starting with benzene as the only aromatic starting material, devise a
437 Predict whether the following substituents on the benzene ring are likely to be ha para directing or meta directing and whether they are like to be ring activating or ring deactivating deact vabang a) - NH(CH 4.38 For each of the monosabstituted benenes shown below, (1) Indicate whether the substituent is ortho, para directing or meta directing (2) Draw the structure of the main monosubstitution product for each of the reactions indicated orth. OCH3 + HCl -OCHE (fecutulys ortho...
Label the following as activating (A) or deactivating (D), and then also as ortho/para directors (OP) or meta directors (M). Write the answer below each group. N "Here with other ty A/D? = = = = OP/M? = f) Using resonance structures, explain why a nitro group is "meta-directing" (i.e. does the nitro group actually affect the meta positions?) g) As mentioned in class, the halogens are a bit anomalous as substituents on the aromatic ring: they are deactivating groups,...
1. please check what is wrong. Thank you!
Determine the product formed when each compound is treated with Br2 and FeBr3. Drag the atom labels to their appropriate positions. CN Atom labels H H Br Br2 A. FeBr Br H OH OH Br Br. Br2 FeBr3 H H Br Br H Br2 FeBr H1 H Reset T Rank the compounds in each group in order of decreasing reactivity in electrophilic aromatic substitution. CI Decreasing reactivity Rank the compounds in each...
THESE ARE THE 6 reagents
1) 1-naphthol
2) 4-bromophenol
3)phenol
4) anisol
5) acetanilide
6) diphenyl ether
rates of electrophilic aromatic substitution lab using bromine. 1. (3 pts.) Draw the structures of all six reactant arenes that will be used in this lab 2. (6 pts.) Beneath each structure you have a. If the substituent is ring b. If the electrophile will be drawn in question 1, note the following: activating or deactivating directed to an ortho, meta, and/or para...
Question 3
1s 3 ORTHO Today we learned about adding a second group to a mono-substituted benzene ring. Any group on a benzene will affect the rate of the reaction (activated or deactivated relative to benzene) and the regioselectivity Where does the electrophile add? Ortho? Meta? Para? Some combination thereof? We found that EDGs (electron-donating groups) direct the electrophile to the ortho and para positions while EWGs (electron-withdrawing groups) direct the electrophile to the meta position. Now, it is time...
on T. Maitiple choiee. Select the best anaver. (0.5 points each) i. Which statement below is true the aromatic substitution involving the bromina of benzene? znBry acts as the Lewis acid B) Feßr, acts as the Lewis base c) Br, acts as nugaed aromatic ring D) n-electrons of benzene act as the electrophile E) FeBr, acta as the Lewis acid. a what is rue about the rate and the najor predust of nitration of the methoxybenzene? A) Proceeds more rapidly...
2. D type and strength of each substituents as activating(A) or outcome as ortho-para (O/P) or meta(M) directors. (6 pts) you expect an electrophile to be attached to the ring You must identify the deactivating(D) and also the expected regiochemical 3. Use aromatic, non aromatic or antiaromatic concepts to explain the reactions or molecules shown (6 pts) Provide a curved arrow mechanism to show the formation of a aromatic carbocation intermediate Show the final product H-I The pK,values for the...
Lumili alle for the following compound? - (CH)CHCH.COCH,CH, a. 2-methyl-4-hexanone c. 2-methyl-3-hexanone b. 5-methyl-3-hexanone d. ethyl isopropyl ketonel. 25-Identify the directing effect of the ring substituent in the following reaction: BO, HBO. (a) o.p., activating (b) m-, deactivating (c) o.p., deactivating (d) None of these 26--Ketones are easily reduced to CH3-C-CH3 a-Secondary alcohol b- Primary alcohol c- to acetaldehyde d- to carboxylic acid 27-. What is the structure of the azo group? a-N- b-N-N- C-NEN- d-NEN- 28-What class of organic...
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