hich of the following statements about the reactions of alkyme A) The characteristic reactions of alkyl...
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether, (CH)1COCH CH, in acidic conditions. What would happen to the rate of the reaction if the concentration of ethanol was doubled? A) The rate remains the same. B) The rate decreases by a factor of 2 C) The rate increases by a factor of 2. D) The rate increases by a factor of 4. Circle the following alkyl halide that will undergo the fastest...
16. Which of the following is correct regarding Sy2 reactions of alkyl halides? A. Secondary halides react faster than primary halides. B. Rate of reaction depends on the concentrations of the alkyl halide only. C. Favored in polar aprotic solvents D. Results in a racemic mixture
For letters h & i : For each of the following reactions, predict the major mechanistic pathway (SN1/SN2/E1/E2) and the major organic products 1. (cont.) (h) НСОН CHB -CHBr HCOH - (0) CH,CH,CH,CH,Br- NH 2. For each of the following indicate which reaction will occur faster. Explain your reasoning. (No credit will be given for guesses) (a) The reaction of (CH),CBr with 0.001M aqueous NaOH or 0.10M aqueous NaOH (b) The reaction of 2-bromobutane with NaOH in DMSO or NaSH...
Uop Which of the following statements are true halides (RX). ve about E1 reactions of alkyl a) Rate = k (base) b) Rale = k [base] (RX}" c) Rate = k (RX) d) The reactions occur in two distinct steps e) Rearrangements do not occur A. ad B. be coce D. c d
17. Which of the following statements is true? A. An Sw1 reaction always proceeds faster than an S2 reaction. B. An Sw2 reaction is not stereospecific C. Good alkyl halide substrates for an E1 reaction are also good for an E2 reaction. D. Increasing the alkyl halide concentration enhances the reaction rate of an Sw1 reaction but not that of an E2 reaction. 18. For the following reaction, what happens to the reaction rate if the concentration of NaN, is...
1. Which of the following structures is/are a secondary alkyl halide? (a) I and II (b) II and V (c) I, II and V (d) IV only (e) I, II and III 2. Which of the following is/are aprotic solvent(s)? Choose all correct answers. (a) (b) (c) (d) (e) (f) 3. Which of the following carbocations, if formed, is (are) likely to undergo rearrangement through a hydride shift? (a) I (b) II (c) III (d) I and II (e) II...
6. Which of the following alkyl halides would afford the indicated product upon reaction with sodium ethoxide? Khat K A. B. II C. III D. IV 7. Predict the product of the following reaction: H2Cro4 (excess) de bygge ! A.1 B. II C. III D. IV E. V 8. Predict the product for the following reaction: HOOH NH H,O* 38 5 5 AT B. 11 C. III D. IV 9. Predict the product for the following reaction: CH,CH,OH (excess) H2SO4...
20) Which of the following statements is true about SN1 reactions of alkyl halides? A) The reactions are favored by polar solvents. B) The reaction occurs via a one-step back-side attack. C) Complete inversion of configuration occurs. D) Reaction rates depend only on the concentration of the nucleophile. E) The reactions are favored by nonpolar solvents.
Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. Methanol to + + NaOCH3 NOCH Mothands t º + HOCH • NAGI HOCHZ + NaCl OH NaHCO3 o + H2O + CO2 + Nal a = Proton transfer b = Lewis acid base c = Radical chain substitution d=Radical chain addition e = Electrophilic addition f=E1 Elimination g=E2 Elimination h=Syl Nucleophilic substitution i= Sy2...
reactions generally give 6. According to more stable alkene product. 7. Elimination of Alkyl halides to yield alkenes occur by three mechanisms 8. In E1 bond break occurs first. 9. In ElcB bond break occurs first. Vocabulary Polar, ElcB, Nucleophilie, E1, Grignard's Reagent, E:2, Aprotic, Zaitsev's rule, Carbocation, Gilman reagents, acidic, C-H, C-x Q3. Write the formula of following groups. (Marks 12) Alkyl Group ii. Alkynyl Group ii. Vinylic Groupiv. Allylc Group Which of the four groups mentioned in Q3...