11. What is the rate law for the following Sn1 reaction? + H2O
Which of the following could represent the rate law for an SN1 reaction? a) Rate = k[A] b) Rate = k[A]2 c) Rate = k[A][B] d) Rate = k[A][B]2 e) Rate = k[A]2 [B]2 Please explain which is the correct answer and why? Thanks
What is the rate law for SN1 reaction? rate k[Base] rate k[RX][Base] rate k[RX] rate kinucleophile] rate k[RX[Nucleophile
The following rate data are consistent with what kind of reaction? Stion 11 The following rate data are consistent with what kind of reaction? (Think reaction kinetics and rate laws). + Naci - trial conc. conc. relative rate 0.1 M 0.2 M 0.2 M 0.1 M 0.1 M 0.2 M OSN2 reaction O SN1 reaction O E2 reaction O E1 reaction
The following rate law could be possible for which of the following mechanisms? E1 E2 SN1 SN2 E2 and SN2 Rate k
85, Consider the following Sn1 reaction. CH3 CH3 CH3-c-CH2CH3 + H2O + CH3- OH2 a. Draw a mechanism for this reaction using curved arrows. b. Draw an energy diagram. Label the axes, starting material, product, E., and Δ" Assume that the starting material and product are equal in energy. c. Draw the structure of any transition states. d. What is the rate equation for this reaction?
5) For an Sn1 reaction what is the reaction rate order? How many steps are in the reaction? Which step is the slow step and why is it the slow step? What happens if you form a chiral center when performing an Sn1 reaction?
For the reaction of Pt(NH3)2Cl2 + H2O --> Pt(NH3)2(H2O)Cl+ + Cl- the rate law was given as rate=k[Pt(NH3)2Cl2] with k=0.090hr-1. Calculate the initial rate of reaction when the concentration of Pt(NH3)2Cl2 is (i) 0.010M (ii) 0.020M (iii) 0.040M
8. Find the rate law of the reaction: keff 3HNO2 H2O + 2NO + H+ + NO, If the first two of the following steps rapidly attain equilibrium and the third step is slow: 3HNO2 H2O + NO + NO2 2N02 N204 HNO3 + H+ + NO; HO + N204 { Note: ki/k-1 = Ky and k2/k2 = K2} A) K.Kak3 [HNO2]/[NO] [H20] B) Kik2 [HNO2]/[NO] [H2O] 1 + FRA 1
Which of the following alkyl halides would react the fastest with H2O in Sn1 reaction? CH3CH2CH2CH2Br, (CH3)2CHCH2Br, CH3CH2CH(CH3)Br, (CH3)3CBr Multiple Choice CH3CH2CH2CH2Br O (CH3)2CHCH2B O CH3CH2CH(CH3)Br O (CH3)3CBI O