Question

A)

Use the References to access important values if needed for this question. Enter electrons as e. Use smallest possible intege

B)

Enter electrons as e. A voltaic cell is constructed from a standard Cd2+ Cd half cell (Ered = -0.403V) and a standard Fe3+Fe2C)

Enter electrons as e. A voltaic cell is constructed from a standard H+H, half cell (Eºred = 0.000V) and a standard Fe3+ Fe2+

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Answer #1

Lower the value of standard reduction potential, then the given electrode acts as anode and higher the value of standard reduction potential, then the given electrode acts as cathode.

A. The anode half reaction (oxidation): Mn(s)    -----> Mn2+(aq) + 2e-

The cathode half reaction (reduction):   Fe2+(aq) + 2e- ---> Fe(s)

The spontaneous cell reaction : Mn(s)   + Fe2+(aq) ---> Mn2+(aq) + Fe(s)

E0cell = Ec - Ea = -0.440-(-1.180) = 0.74 V

E0 cell > 0

B.    The anode half reaction (oxidation): Cd(s)    -----> Cd2+(aq) + 2e-

       The cathode half reaction (reduction):   Fe3+(aq) + 1e- ---> Fe2+(aq)

       The spontaneous cell reaction : Cd(s)   + 2Fe3+(aq) ---> Cd2+(aq) + 2Fe2+(aq)

E0cell = Ec - Ea = 0.771-(-0.403) = 1.174 V

E0 cell > 0

C. The anode half reaction (oxidation): H2(g)    -----> 2H+(aq) + 2e-

       The cathode half reaction (reduction):   Fe3+(aq) + 1e- ---> Fe2+(aq)

       The spontaneous cell reaction : H2(g)   + 2Fe3+(aq) ---> 2H+(aq) + 2Fe2+(aq)

    E0cell = Ec - Ea = 0.771-(0) = 0.771 V

E0 cell > 0

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