6) The original position of the marked carbon in glucose is at postion-3.
5. (6 points) The glycosidic linkage of the following disaccharide is: HO HO ΓΗ HO HO...
#47 What type of glycosidic linkage connect this disaccharide? Снон о П 1 OH HO H OH нон, H HO CH OH Oa-1,4 ОВ-1,2 Oa-1,2 ОВ-1,4 Next >
3. a) Cellobiose is a disaccharide with two glucopyranose rings connected with a B1-4 linkage. Based on this information, draw cellobiose at right: b) This linkage is similar to which polysaccharide? c) Give a balanced reaction for the hydrolysis of cellobiose. Draw all structures: 4. What type of linkage is in each disaccharide below? Give the number of the each carbon linked in the glycosidic bond, and the a or ß chirality for each anomeric carbon (e.g., a1-4) НО. А...
Homework 4 (25 pts total) Due Thursday, February 20 ne molecule depicted below is a disaccharide. Do the following (8 pts): a. number the carbons (1-6) in each ring b. label the glycosidic linkage with an arrow and indicate the type (e.g.: B-1,4) c. draw the two monomers that would result from hydrolysis of this disaccharide. OOH Нон-су анон (CH₂OH ОН o R How do I tell if this is a or B and do I have the carbons #ed...
5) Predict the major product of the following reactioll HO, HO BH D) IV C) III B) II 6) Predict the major product of the following reaction. H50, L H20 H2SO4 7 that Holo A) I B) II II D) IV 7) Predict the major product(s) of the following reaction. w HBr A) Only I and II C) Only III and IV B) Only I and IV D) Only II and III
38.) Which of the following is a pyranose ring? CH OH CH,Ho H OH OH Індон A) I only B) II only C) Both I and II are pyranose rings. D) Neither I nor II are pyranose rings. 39.) In the pyranose form of D-glucose, the-OH on the anomeric carbon atom in the a-form is to carbon 6, while in the B-form it is to carbon 6. A) trans, cis B) cis, trans C) trans, trans D) cis, cis 40.)...
50. For the following compound how many different signals would you see in the proton NMR? (Assume that you can see them all.) A) 4 B) 5 C) 6 D) 7 E) 8 . An organic compound absorbs strongly in the IR at 1687 em. Its 'H NMR spectrum consists of two signals, a singlet at 2.1 ppm and a multiplet centered at 7.1 ppm. Its mass spectrum shows significant peaks at m/z 120, m/z 105 and m/z 77. This...
Carbohydrates are important biomolecules. They are also called saccharides C (H2O) Simple sugars are polyhydroxylated (OH) aldehydes and ketones (C=O). There are multiple classifications, based on length of parent carbon chain, the position of C=0 in chain and the stereochemistry. Complex carbohydrates have multiple simple sugars linked together and polysaccharide are polymers of simple sugars (a) (1) Identify the anomeric carbon in the following structure? Is it in the a or B form? H OH HOTT H OHH OH (ii)...
(5 Marks) B. Answer the questions based on the structures given below i. ii. нонс нонс OH CH HOR OH HO CHOH CH, OH CH OH HO HOM H -OH CH, OH c. Identify the compounds ii, iii and iv as D or L. Explain how you came to this conclusion (2 marks) d. Draw the Fischer projection, enantiomer and indicate which carbons are chiral or achiral for the compound ii. (3 marks) e. Among the compounds iii and iv...
I need some help to answer these following questions. Thanks. 41. Which molecule(s) is/are aromatic? I1 IV (A) I only (C) I, III, and IV (B) I and IV (D) I, II, III, and IV OH OH 42. Which Fischer projection represents this structure? HO OH OH H CHO CHO (A) H-OH (B) HOH HOH CH2OH CH2OH CHO HOH CHO но -н CH2OH CH2OH 43. Which is a product of this ozonolysis reaction? 1.03 2. (CH3)2S H O I BHs/THF...
(e) 2-chloro-6-isopropyleyclohexanone auoUPYau 9. Which of the following molecules contain one chiral carbon? సాని nlo thiral OH HO но -NH HO но II II IV (a) I only (b) I and II c) I, II, III, and V (d) I, II, IV, and V (e) all of them CHE120 RRC S19 E2sample