Practice Problem: could give richedge of chemica use your knowledge of chemical shifts, integration and number...
A variety of spectra for an organic compound with molecular formula C10H16O are presented below. The experimental accurate mass using (+) APCI source is 153.1280 u. The 1H, 13C, COSY, HSQC and HMBC NMR spectra are given in the following slides. Propose a structure for this unknown and answer or address the following questions or requirements: d. If there are still any questionable assignments, propose additional NMR experiments which would solve those questions and briefly explain specifically what correlations you...
A variety of spectra for an organic compound with molecular formula C10H16O are presented below. The experimental accurate mass using (+) APCI source is 153.1280 u. The 1H, 13C, COSY, HSQC and HMBC NMR spectra are given in the following slides. Propose a structure for this unknown and answer or address the following questions or requirements: a. Using the most abundant isotopes of C, H and O, what are the errors in ppm and milli-Daltons for the experimental accurate mass?...
7. What kind of carbons correspond to these chemical shifts? 8. Based on this analysis, the unknown might contain the following substructure: UN (43 MIL.) 10.02s, 1H), 7.716.J-2 Hz. ) 2.0 11.5 11.0 10.5 10.0 9.5 9.0 8.5 8.0 7.5 7.0 6.5 6.0 4.0 3.5 3.0 2.5 20 15 100.5 0.0 -0.5 -1.0 -1.5 -2. 5.5 5.0 4.5 fl (ppm)
3. Based on the integration of the peaks, what is the relative number of protons which make up each signal? 4. Identify any common splitting patterns. (ie. Isopropyl, ethyl, etc) UN (43 MIL.) 10.02s, 1H), 7.716.J-2 Hz. ) 2.0 11.5 11.0 10.5 10.0 9.5 9.0 8.5 8.0 7.5 7.0 6.5 6.0 4.0 3.5 3.0 2.5 20 15 100.5 0.0 -0.5 -1.0 -1.5 -2. 5.5 5.0 4.5 fl (ppm)
1. How many different types of protons appear to be present? What are the chemical shifts for these protons? What does this indicate (if anything) about the electronic environment of the protons? 2. What are the multiplicities for each peak? UN (43 MIL.) 10.02s, 1H), 7.716.J-2 Hz. ) 2.0 11.5 11.0 10.5 10.0 9.5 9.0 8.5 8.0 7.5 7.0 6.5 6.0 4.0 3.5 3.0 2.5 20 15 100.5 0.0 -0.5 -1.0 -1.5 -2. 5.5 5.0 4.5 fl (ppm)
label the spectrum OTBS Meo Yome Me H NMR spectrum (CDC13, 400 MHz) 8.5 8.0 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 f1 (ppm) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 -0.5 18C NMR spectrum (CDCI, 100 MHz) 210 200 190 180 170 160 150 140 130 120 110 100 fi (ppm) 90 80 70 60 50 40 30 20 10 -10
What compound gave off this spectrum? After classification tests, I confirmed unknown was a primary alcohol. originally thought that this spectrum aligned with 1-pentanol... not so sure now. Please help! 1-2H setter ppm 1.6 Ppm 0.90 ppm Courbe singlet sextet s neighboo 21 groups quintet group 4 neighbor 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 ppm 1.97 5.05 3.00
CHEM210 Name 3. Based on the molecular formula and spectrum below, propose a structure to analyze each peak using the information on chemical shift, integration, and multiplicity lean role. The insets are expanded views of each peak so that the muplicity is clear. propose a structure for the molecule. Show your work it, integration, and multiplicity learned in the tutorial. Molecular Formula: CH..0: Predicted 1H NMR Spectrum 34 4.15 4.10 ppm 4.05 1.30 1.25 1.20 ppm 1.15 1.00 OH 2.50...
Fill out the tables below of the starting material and pure product by using the given NMR spectrums. Identify if the pure isomer of methyl nitrobenzoate as ortho, meta, or para. Complete the table below using your proton NMR spectrum of your starting material. Be sure to include all peaks. Note: The table is expandable. Use the structure below for the letter assignments in your table. Splitting Integration Assignment Peak (ppm) Other Notes -7.95 -7.92 0627 -787 785 7.30 751...
5. Based on this analysis, the compound might be or contain the following substructure: 6. How many different types of carbons appear to be present? What are the chemical shifts for these carbons? UN (43 MIL.) 10.02s, 1H), 7.716.J-2 Hz. ) 2.0 11.5 11.0 10.5 10.0 9.5 9.0 8.5 8.0 7.5 7.0 6.5 6.0 4.0 3.5 3.0 2.5 20 15 100.5 0.0 -0.5 -1.0 -1.5 -2. 5.5 5.0 4.5 fl (ppm)