Question

В. Titration of KHP Trial 1 Trial 2 Trial 3 Trial 4 0.321ps 0.00 mL 20mL Q302. 0.334 0.00 mL .10 mL v.O mL 0.328 O.00 mL Ke.2
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Answer #1

We have , No. of moles = Mass / Molar mass

\therefore No. of moles of KHP = Mass of KHP / Molar mass of KHP

Molar mass of KHP = 204.22 g/mol

Trail 1 Trail 2 Trail 3 Trail 4
No. of moles of KHP

= 0.326 g / 204.22 g/mol

= 0.001596 mol

= 0.302 g / 204.22 g/mol

=0.001479 mol

= 0.334 g / 204.22 g/mol

= 0.001635 mol

= 0.328 g /204.22 g/mol

= 0.001606 mol

Consider reaction KHP + NaOH phpG0ciMi.png KNaP + H2O

From reaction, 1 mole KHP reacts with 1 mole NaOH. Therefore, we can write

No of moles of KHP = No of moles of NaOH

Therefore, we get no .of moles of KOH equal to no. of moles of KHP

Trail 1 Trail 2 Trail 3 Trail 4
No. of moles of NaOH

0.001596 mol

0.001479 mol

0.001635 mol

0.001606 mol

We know that, Molarity = No of moles / volume of solution in L

Trail 1 Trail 2 Trail 3 Trail 4
Volume of NaOH in L 16.20 ml = 0.0162 L 15.10 ml = 0.0151 L 16.10 ml = 0.0161 L 16.20 ml = 0.0162 L
[NaOH]

= 0.001596 mol / 0.0162 L

= 0.0985 M

= 0.001479 mol/0.0151 L

= 0.0979 M

= 0.001635 mol / 0.0161 L

= 0.102 M

= 0.001606 mol / 0.0162 L

= 0.0991 M

Average [NaOH]

= ( 0.0985 + 0.0979 + 0.102 + 0.0991 ) / 4

= 0.0994 M

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