6.3 un pas mujecu a pair of scissors Show the planes and centers of symmetry (if...
A. Enantiomers: Certain substances have the unique property of rotating the plane of plane-polarized light. Such light rotation is detectable with the aid of a polarimeter. In order for a molecule to be optically active it must be chiral. Chiral objects lack a plane of symmetry and are non-superimposable on their mirror images. A sp?- hybridized carbon atom can fulfill these requirements if all four of its substituents are different. 1. Methane a) Prepare a methane molecule and then substitute...
3. Cyclic compounds The presence of the ring in all but very large ring cyclic molecules prevents full rotation of the ring atoms. For this reason, stereoisomerism may also occur in cyclic molecules. a) Prepare a model of cyclohexane, C6H12. Draw the condensed formula. b) Build a model of methylcyclohexane (C7H14) by replacing one of the hydrogens of cyclohexane with a methyl group. Draw the skeletal formula for methylcyclohexane. 2 c) How many different isomers exist for methylcyclohexane (CyH34)? d)...
Key concepts: molecular represenations, stereolsomers, RS enantiomeric excess, IPAC naming covention Provide the IUPAC name for each of the following molecules 0% HJC BM How similar are the names for B and C, even though there is the single change to the structure 2 Rank the priorities of these functional groups and substituents using Cahn-Ingold-Prelog nomenclature. Highest priority will be 1 and lowest will be 5; show your rationale CH:CH:CH CH CHCH:CH CHs,-SCH,-CH: CH:CH:CHCH CHCH, -CH2NHOH,-CH:NO Draw dash/wedge representations for...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition of the proton to one face of the alkene with simultaneous delivery of a bromide ion from a different molecule of H-Br. 11. Which compound is the strongest nmucleophile for reaction of methane methanesulfonate (CHOS0.CH) in methanol at room temperature? (You may assume that everything is soluble in methanol) (A) potassium bromide (B) cesium iodide (C) sodiam chloride (D) lithium flaoride 12. Which proton...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...