Draw the Newman structures for 1,2 dimethycyclohexane , 1,3 dimethylcyclohexane and 1,4 dimethylcyclohexane. Please draw the...
rank cis-1,2-dimethylcyclohexane, cis-1,3-dimethylcyclohexane and cis-1,4-dimethylcyclohexane in increasing order of stability.
Draw the newman projections for 1,4 dimethylcyclohexane for cis and trans with ring flip. there should be 4 newman projections.
PART B: Cyclohexane Procedures: 1. Make a model of cis-1,2-dimethylcyclohexane and trans-1,2-dimethylcyclohexane. Do a ring flip of both *Draw the two conformation of the cis and trans cyclohexane structures above *List the number of axial and equatorial substituents for both the cis and trans *Which isomer is more stable overall, cis or trans? Why? 2. Make a model cis-1,3-dimethylcyclohexane and trans-1,3-dimethylcyclohexane. Do a ring flip *Draw the two conformation of the cis and trans cyclohexane structures above *List the number...
Draw newman projections of 1-2 cyclohexane and 1-3 cyclohexane cis and trans. there should be 8 total newman projections. 1,2 and 1,3 dimethylcyclohexane is what it is supposed to be The 8 newman projections include ringflips of cis and trans.
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain these factors. 7. The conformation of cyclobutane is slightly folded. Folding gives partial relief from the eclipsing of bonds, as shown in the Newman projection. Compare this actual structure with the hypothetical planar structure. Draw the relevant structures. 8. trans-1,2-Dimethylcyclobutane is more stable than cis-1,2-dimethylcyclobutane, but cis-1,3- dimethylcyclobutane is more stable than trans-1,3-dimethylcyclobutane. Use the molecular models to find the reasons for...
Cis-1,2-dimethylcyclohexane and cis-1,4-dimethylcyclohexane have very similar heats of combustion. However, cis-1,2-dimethylcyclohexane is slightly higher. Why?
4. Draw the following cycloalkanes as two-dimensional structures, using wedges and dashes: trans-1-bromo-2-methylcyclopentane cis--chloro-3 ethylcyclohexane trans-1,3-dimethylcyclohexane trans-1-bromo-3 ethylcyclobutane cis-1-ethyl-4-methylcycloheptane cis-1-isopropyl-3- methylcyclopentane
In each of the cases below, which isomer is more stable? a) 1,4-dimethylcyclohexane (cis/trans?): b) 1-bromo-2-methylcyclohexane : (cis/trans?) c) 1,3-diethylcyclohexane (cis/trans?)
11. Build the chair and boat conformations and identify the most stable conformation. Identify the 1,3-diaxial interactions. 12. Draw the most stable conformation of (a) ethylcyclohexane (b) 3-isopropyl-1,1-dimethylcyclohexane (c) cis-1-tert-butyl-4-isopropylcyclohexane 13. Draw all possible conformations of 1,4-dimethylcyclohexane and identify the most stable conformation 14. (a) Draw both chair conformations of cis-1,2-dimethylcyclohexane, and determine which conformer is more stable. (b) Repeat for the trans isomer. (c) Predict which isomer (cis or trans) is more stable. 15. (a) Draw both chair conformations...
Laboratory Work 1. Draw the skeletal formulas and make models of the three constitutional isomers of C5H12. 2. Draw Kekule structures and make models of all the constitutional isomers of C2H4Cl2. 3. Draw Kekule formulas and make models of ethane, ethene, and ethyne. How does the geometry of their structures differ? Which compound contains sp hybridized carbons? 4. Draw and label the Newman projection and make the model of the anti-conformation of 1,2-dibromoethane. Rotate around the carbon-carbon bond...