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Choose the major product for each reaction. Be sure to include stereochemistry where applicable. racemic HBO,...
9. Predict the major products for the following reactions. Show the stereochemistry of the products) when applicable.. (a) HIB ROOR (1) Hg(OAc), HO (2) NaBH (1) BH, THE (2) 1,0, OH Br. H.O Pt (1) Oso (2) NaHSOHO (1) 03 (2) DMS (1) CHCO,H (2) H0+ Page 2 of 2
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Predict the product for the following reaction. Include stereochemistry where applicable. I'm not sure where to begin with this one. n. NH I. NaOH /EtOH II. (CH3 2)4 III. NaOH H,O IV. acetyl chloride V. 1) LiAlH4. 2) H20
For each of the following reactions, provide the product with proper stereochemistry if applicable. In addition, draw the arrow-pushing mechanism for the reaction. 1. CH HCI 2. CH HBr ROOR 3. CH, Н,0 H, SO 4. CH3 1. Hg(OA), 2. NaBH + 5. CH, 1. BH, THF 2. HO, NaOH
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. (i) -COH На (i) Pd/C OsO4 NaHSO3, H20 н СHC1, КОН (iv) i) ВН, THF CECH in) H,О, NaOH Li, NH3 (liquid) (vi) XX H/H20 (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. он BH3, THF i)H202 NaOH он )Hg(OAc)2 H20 i)NaBH (iii CH O i) Zn/H +
predict the major product for each transformation below,indicate the stereochemistry where appicable.assume all reaction will take place (28 points) Predict the major product(s) for each transformation below. Indicate the stereochemistry where applicable. Assume that all the reactions will take place. BE TEA, CH,Cl2 heat hv NaNH, DMF De Cl,H,O OH 1. Hg(OAc)2(aq). 2. NaBH(aq) CICCIA 1.03,CH,CI 2. S
plete the following reactions, providing the proper stereochemistry where required. If more than one product is possible, indicate the major product. a) ros. Br CH3 -CH; 1) BH THE 2) H20. NaOH -CH₂ ROOR RCO,H t.tt 1T 1) Hg(OA), H2O 2) NaBH 1. Provide the IUPAC name for the following molecule: 2. Draw the structure of Z-4-Bromo-5-methyl-4-hepten-2-yne: 3. Write down the major product(s), or the other reactant(s), of the following rea stereochemistry (wedge-and-dash) where appropriate: Xs HBr
Fill in the products in the reaction spiderweb below. Be sure to depict proper stereochemistry where appropriate. Short Answer Section -12.5 points to depict 5. Spiderweb ts.s pts, 0.5 pts/box) total. the below. Be sure Fili n the products in reaction sp substitution substitution product(s) only product(s) only CH3OH HCI H2SO. H2O E-butoxide NaOH major elimination major elimination product only product only 1 BH 1. Hg(OAc)2, H2O 2. H202. NaOH 2. NaBH4 1 NaH 2. CHal *NaH will deprotonate
Name: 3. Draw the major product for the following reactions (draw both products if racemic): CH3 НСІ 1. BH -THE 2. HOy, NaOH . CH3 Bra CH2Cl2 (solvent) CH3 Oso H₂O2 1. Hg(OAC)2, H0 2. NaBH4 HBr, peroxides
Q 2 - Fill in the boxes with the product(s) for the following reactions. Draw only the predominate regioisomer and indicate the stereochemistry where appropriate. If a racemic mixture is formed, you may indicate this using a wavy line www or mark the chiral center with an asterisk (*), and write racemic in the box. You may also draw both enantiomers and write RACEMIC in the box. 1.BH3 2, H2O2, NaOH 1. Hg(OAc), H20 2. NaBH4 H3C CH3 1.BH 2....