14. Propose a structure for a molecule of formula CssCl which gave the following 'H NMR...
15. Propose a structure for a molecule of formula CaH Clwhich gave the following 'H NMR spectrum PPM 16. Propose a structure for a molecule of formula CaHiCi which gave the following 'H NMR spectrum. PPM
35. Propose a structure for a molecule of formula CsHi0O2 which gave the following 'H NMR spectrum. (3) 3 C--C -01 sela 2 PPM 36 Propose a structure for a molecule of formula CigHa which gave the following H NMR spectrum. (3) K HC -2-1 3H 2H 2 2H seatar 0 PPM 37. Starting with benzene and any necessary reagents, outline all steps in the syntheses of two of the following molecules (6) Bonus 2 points for a third synthesis...
16. Propose a structure for a molecule of formula CaHsCl which gave the following 1H NMR spectrum. PPM 17. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 148, an IR peak at 1680 cm'and gives the following H and 13C NMR spectra 3H зн 2H 2H 2H 3 5 2 7 6 4 PPM 160 140 180 60 220 200 20 0 120 100 80 40 PPM -
4. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. 33 N - PPM 5. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. doublet 2...
9. Propose a structure for a molecule that has the following 'H NMR spectrum and a molecular formula of C3H30. The peak at 2.28 disappears when D20 is added to the sample. (5 points) бH HSP-03-214 ppm
21. Propose a structure for compound HALLOWEEN with a formula CsH1002 with the following 'H NMR spectrum and IR spectrum. NAVENTER Area Chem Shift Splitting singlet multiplet multiplet doublet triplet Ppm
Propose a reasonable structure based on the molecular formula, the 'H NMR, and the proton-decoupled *C NMR data below. The unknown compound has a molecular formula of C7H160 and * = CH2 by DEPT. 'H NMR 3H 8H HC NMR 2H (CH3), Si 3.5 0.0 40 3.0 2.5 2.0 1.5 1.0 0.5 300-MHZ 'H NMR spectrum ppm (8) "C NMR spectrum ppm (5)
9. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 102 (M), IR peaks at 1740 and 1150 cm which gave the following 'H NMR spectrum.) 2 PPM
1H NMR 6. Propose a structure for the compound CzH.O with the following 'H NMR spectral data. 2H 1H 3H 1110 H ppm 7. Propose a structure for the compound C2H60, with the following 'H NMR spectral data. (Note this is the same molecular formula as the previous question) ppm 8. Propose a structure for the compound C,He with the following 'H NMR spectral data. SH2H 1H ppm 9. Propose a structure for the compound CxHyN with the following 'H...
4. Propose a structure for each molecular formula using the provided H NMR spectrum. (a) CH30 6H IH 1H PPM (b) C6H120 ЗН PPM (c) CaHgBr 2H PPM (d) C&H N 2H 2H PPM