The compound is saturated and can be an alcohol(-OH) , as the -OH proton is labile with D2O and gets exchanged . The resonance of -OH proton also occurs in the region 2- 5 ppm.
Thus we can say the compound is isopropanol CH3-CH(OH) -CH3
From the 1HNMR
we see both the -CH3 as doublet at 1.1 ppm,
the middle CH , is seen as a heptet at 4.0 ppm(deshielded due to the attached -OH)
and the oH proton at 2.2ppm that disappears on addition of D2O.
9. Propose a structure for a molecule that has the following 'H NMR spectrum and a...
15. Propose a structure for a molecule of formula CaH Clwhich gave the following 'H NMR spectrum PPM 16. Propose a structure for a molecule of formula CaHiCi which gave the following 'H NMR spectrum. PPM
16. Propose a structure for a molecule of formula CaHsCl which gave the following 1H NMR spectrum. PPM 17. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 148, an IR peak at 1680 cm'and gives the following H and 13C NMR spectra 3H зн 2H 2H 2H 3 5 2 7 6 4 PPM 160 140 180 60 220 200 20 0 120 100 80 40 PPM -
4. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. 33 N - PPM 5. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. doublet 2...
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A compound with a molecular formula C5H10O has the following 1H NMR spectrum. Provide a structure that is consistent with this spectrum. 3. A compound with a molecular formula CsHioO has the following 'H NMR spectrum. pound with a molecular formula CsHioO has the following H NMR Propose a structure for this compound. PPM
Propose a reasonable structure based on the molecular formula, the 'H NMR, and the proton-decoupled *C NMR data below. The unknown compound has a molecular formula of C7H160 and * = CH2 by DEPT. 'H NMR 3H 8H HC NMR 2H (CH3), Si 3.5 0.0 40 3.0 2.5 2.0 1.5 1.0 0.5 300-MHZ 'H NMR spectrum ppm (8) "C NMR spectrum ppm (5)
1H NMR 6. Propose a structure for the compound CzH.O with the following 'H NMR spectral data. 2H 1H 3H 1110 H ppm 7. Propose a structure for the compound C2H60, with the following 'H NMR spectral data. (Note this is the same molecular formula as the previous question) ppm 8. Propose a structure for the compound C,He with the following 'H NMR spectral data. SH2H 1H ppm 9. Propose a structure for the compound CxHyN with the following 'H...
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Determine the structure of the following given the spectrum and molecular formula CzH02 11 10 9 8 7 6 HSP-03-871 ppm C,H1202 TTTTTTT 11 10 9 8 7 5 2 1 . HSP-03-401 ppm C.H. 11 10 9 8 7 6 5 3 2 10 HSP-00-525 ppm H C HO 12 11 10 9 8 7 4 3 2 1 0 - 1 6 5 ppm HSP-02-753