Question

Determine the unknown of these NMR graphs using table below, table below is just an example, follow table to demonstrate what unknow is

Chemical Shift Integration Splitting # of Neighbors Frequent.

a

0.9 3H TRIPLET 2 CH3-CH2-
b 1.5 2h SEXTET 5 CH3
c 3.6 2H TRIPLET 2
d 3.8 1H SINGLET 0

314 3H 1 X 2.0 4.0 3.0 5.0 6.0 ppm (t1) Unknown 41 CsH&O2 6.081 6.078 6.076 6.073 6.545 93 5.540 5.535 5.529 5.524 1.926 1.92   ketone C_H.O ealc SP3 C-H Sp2 C-H 4800 3000 2008 1000 BRVENUOR 3107 6 2987 66 1453 32 26 1403 54 1164 1021 1014 7 55 832 62 8

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Answer #1

CH3OCH = CHCOCH3

SlNo Chemical Shift Integration Splitting # no of neighbours Frequent
a 1.0 3H Singlet 0 COCH3
b 3.7 3H Singlet 0 OCH3
c 5.5 1H Singlet 0 Alkenes (splitting can occur based on E or Z isomer
d 6.1 1H Singlet 0 Alkenes

Based on the splitting pattern at 5.5 and 6.1 this molecule should exist and E isomer. A doublet is expected at this region of 5.5 and 6.1 if this is existing as Z isomer.

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