The following molecular orbital diagram is for the 2nd period homonuclear diatomic O. It only shows...
Construct an approximate molecular orbital energy diagram for homonuclear diatomic F2. Considering only the valence atomic orbitals on fluorine. Show the sigma and pi interaction between orbitals of the same symmetry and then rank these on your diagram in terms of increasing energy (be sure to draw pictures of the orbital interactions or the final MOs). Write out the electron configuration and determine the bond order of F2.
Upon Inspecting a molecular orbital diagram for homonuclear diatomic molecule, you see that this molecule has electrons in bonding orbitals and 6 electrons in anti-bonding orbitals. What is the bond order for this molecule, and would you predict for it to be stable or unstable? O Bond order - 2 stable Bond order - 1, unstable O Bond order 1, stable Bond order 0, unstable : Bond order 2 unstable
Using the molecular orbital energy ordering for second-row homonuclear diatomic molecules in which the π2p orbitals lie at lower energy than the σ2p, predict the bond order in a molecule or ion with each of the following numbers of total valence electrons.(Use the drawing MO energy diagrams) Will the molecule or ion be diamagnetic or paramagnetic? Part A Determine the bond order in a molecule or ion with 4 valence electrons. Part B Will this molecule or ion be diamagnetic...
13. (14 pts) MO Theory Draw the complete (core and valence) molecular orbital energy level diagram for the homonuclear diatomic molecule Be2. Use standard MO symbols to label the energy levels (That is: o, o, , or n*, as needed, with subscripts indicating which atomic orbitals formed them.) a. Sketch the molecular orbital formed when two 2p orbitals, one each on each Be atom, overlap to form a o antibonding MO b. Using your MO energy level diagram in (a),...
5. Suppose that photoelectron spectroscopy is done on a 2nd-row homonuclear diatomic molecule. Photons with energy 21.21 eV are used, and electrons are ejected with kinetic energies of 11.01 eV, 8.23 eV, and 15.22 eV. (a) Sketch the molecular orbital energy level diagram for the molecule, showing the ionization energies of the three orbitals. Assume that these are the only three filled or partially-filled orbitals and that the molecule is in the ground state. (b) What are the possible identities...
3. Part 2. Show your calculation or explanation for (b) and (c). (a) (3pt) The Molecular Orbital energy diagram of NO (nitrogen monoxide) is given in the right figure. Write the electron configuration of NO molecule in the ground electronic state based on this energy diagram. 6o" Sx 20" 21 Y atom orbitals lo NO molecular atomic (b) (3pt) Determine the bond order of NO molecule. X atom atomic orbitals orbitals (c) (3pt) Which of the following diatomic species has...
1. For the homonuclear diatomic molecules across the periodic table from H2 to Nez (10 molecules in all), make a MO diagram like the figure, and fill in the electrons. Be sure to get the order of the orbitals correct (see Fig. 11.14 of textbook). For each molecule, give the bond order and whether or not it's paramagnetic (unpaired spins). I know this seems like a pretty basic question, but it's important for chemists to have this model embedded in...
Q2. Answer the following questions. compared to O2 and larger? molecule compared to a homonuclear diatomic molecule? describe just the valence bonding in the triatomic molecules a) beryllium dihydride and b) water. a) Why is the aufbau order different for homonuclear diatomic molecules N2 and smaller b) What is different about the nature of the MO diagram of a heteronuclear diatomic c) Provide a minimum basis set of atomic orbitals that would need to be mixed to Q2. Answer the...
1) 2) 3) 4) 5) Use the molecular orbital energy diagram below to answer the questions about bond order for the negative ion By. Number of Bonding Number of Antibonding B2 Valence Electrons Valence Electrons Bond Order This corresponds to: A. Single bond B. Double bond C. Triple bond D. Half of a bond E. Between a single and double bond F. Between a double and a triple bond G. No bond, B2" does not form. boron MO's boron 2p...
0.67/1 pts Question 15 Ad molecular orbital possesses electron density [Select [Select] the nuclei and electrons in the internuclear axis that orbital weaken the bond. Answer 1: above and below Answer 2 not between Answer 3: weaken 0/1 pts t Question 16 Considering only the valence s and pelectrons from the individual atoms, an F2 molecule contains how many electrons in all antibond ing molecular orbitals if it has a molecular orbital diagram as shown below? 0.67/1 pts Question 15...