This question is solved on the basis of hyperconjugative structure of free radical.
16. Within each of the following sets of alkyl radicals, name each radical; identify each as...
16.) Within each of the following sets of alkyl radicals, name each radical; identify each as either primary, secondary, or tertiary; rank in order of decreasing stability; and sketch an orbital picture of the most stable radical, showing the hyper conjugative interaction(s). (a) CH3CH2C·HCH3 and CH3CH2CH2CH2 · (b) (CH3CH2)2CHCH2 · and (CH3CH2)2C·CH3 (c) (CH3)2CHC·HCH3 , (CH3)2C·CH2CH3 and (CH3)2CHCH2CH2· (I put the lone electron after the radical carbon.) Also, my main question is in bold. The rest I know and understand....
1:06 Exit (CH3)3C, CH2=CHCH2, CH3CH2, CH3 , (CH3)2CH Label each radical species above as either: methyl, primary, secondary, tertiary, or allylic. A. [Select ] B. [Select] C. [Select] D. (Select ] E. [Select] Rank the species in order from LEAST stable to MOST stable. [ Select] [ Select] [ Select ]
The figure below shows the structure of several alkyl radicals. Which of the following identifies the correct name for the radical? A CH3- E CH3CH2- A) B = isobutyl B B) D = isopropyl C) F = tertiary butyl CH3CH- F CH3CH2CH- CH3 CH3 C CH3CH2CH2- G CH3CH2CH2CH2- CH3 CH,CHCH2- H CH3C- CH3 CHE D) G = butyl D E) H = secondary butyl
yea i need 4 5 anx 6 ough the following stepe 20 points) The bromination of methane proceeds through Br - 2Br CH. Br. CH: Br AN (per mole) E. per mole) 1100 (kral) 100 LJ (45 kcal) C'H + HBr + 73 kJ (17 kcal) 7911 . CH, Br + Br 112 kJ ( 27 kcal) 7 kcal)79 kJ (19 kcal) 27 kcal)4 kJ (1 kcal Draw a complete reaction-energy diagram for this rea b) Label the rate-limiting step....
Warm up 1. Identify if each compound below is a primary, secondary, or tertiary alkyl halide. 2. Identify the most stable radical of the compound series below (HINT: radicals and carbocations are electron deficient and are similarly stabilized/destabilized by substituents. See Table 8.7) 1B) "O o oo | B) Br ~ ~ ~ "
10 pts Question 6 Rank the following carbocations in order of increasing stability. Identify each of the carbocations as methyl, primary, secondary, or tertiary. CH, CH.CH -ён, сносе сна ін си, пенси, А es es | Select) [Select) < Select) [Select) Select) [Select] 4 Carbocation A: Select] Carbocation B: Select Carbocation C. Select Carbocation D: Select Carbocation E: Select] Carbocation : [Select]
Write the common name for each of the following Part A CHE H-N-CH2-CH2-CH3 Spell out the full name of the compound. Submit Request Answer Part B Spell out the full name of the compound. Submit Request Answer Part C NH Spell out the full name of the compound. Submit Request Answer Part D Classify each compound as primary (1"), secondary (2º), or tertiary (3) Drag the appropriate items to their respective bins. Reset Help NH2 CH, H-N-CH-CH2-CHg Primary (1) Secondary...
1. (3 pts. each) For each of the following sets, rank their relative stability from 1 to 3 where 1 is most stable and 3 is least stable CHs H3C H3C CH2CH3 CH2CH3 CH2CH3 CH-CH3 CH3 CH3 CH2CH3 На CH3 CH3 ,C(CH3)3 C(CH3)3 C(CH3)3 2. (3 pts) In any of the linear molecules above, find and label a pair of substituents that are "gauche" to each other. Label another pair that is "anti." Clearly label the pair n, cirele an...
Model 3: Reactions of Bromine Radical with Various Alkanes For each reaction below, the most likely products are shown. H H H H Rxn I : Br -H H H H H H H H Br H Rxn IV C- H H CHy сн, H,C нC Rxn V BrH н.с CH -сн Critical Thinking Questions 5. Label the carbon radicals in Model 3 as methyl. primary, secondary, tertiary, allyl or benzyl. a) Which carbon radical in Model 3 is closest...
eeWs Page 2 Identify the nucleophile in the following reaction. ROH H, 0+x O o Pas 2 HO+ RX a. X b. н,о° c. ROH d. H,o e. RX eoulav olmaneboseds pietren fom c.er Ho 6. Which free radical is most stable relative to the hydrocarbon from which it is formed? a. CH, CH, CH, b. (сн, ), сн- с. (сH, ), С. d. CH-CH lon fom ayd beoubozg ed neolaoibe o nonudacoqm dpld o oa e. CH2-CHCHCH3 Which of...