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1:06 Exit (CH3)3C, CH2=CHCH2, CH3CH2, CH3 , (CH3)2CH Label each radical species above as either: methyl,...
16. Within each of the following sets of alkyl radicals, name each radical; identify each as either primary, secondary, or tertiary; rank in order of decreasing stability; and sketch an orbital picture of the most stable radical, showing the hyperconjugative interaction(s). a. CH,CHCHCH, and CH CH.CH,CH, b. (CH,CH),CHCH2- and (CH,CH2),ċCH, (CH),CHCHCH3, (CH),"CH,CH, and (CH3),CHCHCH:
16.) Within each of the following sets of alkyl radicals, name each radical; identify each as either primary, secondary, or tertiary; rank in order of decreasing stability; and sketch an orbital picture of the most stable radical, showing the hyper conjugative interaction(s). (a) CH3CH2C·HCH3 and CH3CH2CH2CH2 · (b) (CH3CH2)2CHCH2 · and (CH3CH2)2C·CH3 (c) (CH3)2CHC·HCH3 , (CH3)2C·CH2CH3 and (CH3)2CHCH2CH2· (I put the lone electron after the radical carbon.) Also, my main question is in bold. The rest I know and understand....
2. Rank the following radicals in decreasing order of stability (1-most stable, 5-least stable): CH2 CH3 (CH3)2Ć (CH3)2CH CH3CH2
2). Consider the following intramolecular S2 reaction. no ♡ + HI A) (5 pts) Use the table of Bond Dissociation Enthalpies (at the back of the exam) to calculate the approximate ΔΗπη. B) (3 pts) Is the reaction endothermic or exothermic? Why? C) (6 pts) Draw the Reaction Energy Coordinate Diagram. Label the axes, reactant(s), product(s), transition state(s), intermediate(s), activation energy, and reaction enthalpy. D) (3 pts) In regards to entropy, would you expect the reaction to be favorable, or...