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Please show all work step by step and final answer. Electro-refinement of Gold In the refinement...
Electro-refinement of Gold In the refinement of gold a basic solution of Au(CN)4 is electrolyzed. Gold metal and oxygen gas are produced at the electrodes. Answer questions by selecting the appropriate reaction. Which half-reaction takes place at the anode during this electrolysis? Incorrect O2 + 2H+ + 2e -> H202 Incorrect Au(CN)4 + 3e - Au + 4CN Incorrect Au + 4CN - Au(CN)4 + 3e Correct: 40H - 02 + 2H20 + 4e Which is the overall cell reaction...
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Reactions at Electrodes during Electrolysis Answer the following questions by selecting the appropriate half-reaction. Assume that in each case the experiment is performed in an electrolysis cell having electrodes made of non-reacting material. Which half-reaction will take place at the anode during the electrolysis of 1.0 M H2O2 solution containing 1.0 M H2SO4? O 02 + 4H+ + 4e - 2H20 H202 0 2 + 2H+ + 2e H2O2 +...
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Reactions at Electrodes during Electrolysis Answer the following questions by selecting the appropriate half-reaction. Assume that in each case the experiment is performed in an electrolysis cell having electrodes made of non-reacting material. Which half-reaction will take place at the anode during the electrolysis of molten MgCl2? 20" - Cl2 + 2e Cl2 + 2e - 2014 Mg2+ + 2e Mg Mg - Mg2+ + 2e Which half-reaction will take...
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Electrolysis in Aqueous Solutions -- Overvoltage Refer to data from a table of standard reduction potentials for common half-reactions and/or the following half-reaction to answer the questions below. 52082- + 2e → 25042- E° = 2.01 v During the electrolysis of an aqueous solution of Na2SO4, which reaction occurs at the (platinum) cathode? 2H20 + 2e - H2 + 20H SO42- + 4H+ + 2 H2O + H2SO3 2H20 0...
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Nernst Equation Applied to Half-Reactions The Nernst equation can be applied to half-reactions. Calculate the reduction potential (at 25°C) of the half-cell Cu/Cu2+ (1.8x10- M). (The half-reaction is Cu2+ + 2e Cu.) 1 pts Submit Answer Tries 0/5 Calculate the reduction potential (at 25°C) of the half-cell Mn04 (2.00x10-1 M) Mn2+ (2.50X10-2 M) at pH = 4.00. (The half-reaction is MnO4 + 8H+ + 5e Mn2+ + 4H20.) 1pts Submit...
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Selective Reduction The standard reduction potential for the half-reaction: Sn4+ + 2e + Sn2+ is +0.15 V. Consider data from the table of standard reduction potentials for common half-reactions, in your text. For a galvanic cell under standard conditions, which of the following anodic half reactions would produce, at the cathode a spontaneous reduction of Sn4+ to Sn2+ but not Sn2+ to Sn. Sn- Sn2+ + 2e Sn2+ Sn4+ +...
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Reference Electrodes The Eº value for the following reaction is 0.446 V relative to the standard hydrogen electrode (SHE): Ag2 CrO4(s) + 24 + 2Ag(s) + Cro42 (aq) A chemist wishes to determine the concentration of Cro42- electrochemically. A cell is constructed consisting of a saturated calomel electrode (SCE; which has a reduction potential of 0.242 V relative to the SHE) and a silver wire coated with Ag Cro4 and...
A chemist designs a galvanic cell that uses these two half-reactions: standard reduction potential half-reaction + O2(9)+4 H (aq)+4e' 2H20) = 1.23 V red Ered Fe+. (аq) Fe3(aq)+e = +0.771 V Answer the following questions about thiss cell Write a balanced equation for the half-reaction that happens at the cathode Write a balanced equation for the half-reaction that happens at the anode Write a balanced equation for the overall reaction that powers the cell. Be sure the reaction is spontaneous...
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Consider the following reaction: 2 C2H6(9) + 7 02(9) — 4 CO2(g) + 6H2O(1) Use standard heats of formation from Zumdahl 'Chemical Principles' 8th ed. Appendix Four pp A19 - A21. How much heat is evolved when 5.820 moles of C2H6(9) is burned in excess oxygen. Answer to 4 sig figs. Assume standard conditions. Note that, by convention, a decrease in enthalpy of the system will result in a positive quantity of heat being...
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Electrochemical Measurement of Concentration An electrochemical cell consists of a standard hydrogen electrode and a copper metal electrode. What is the potential of this cell at 25°C if the copper electrode is placed in a solution in which [Cu2+] = 3.6x10-4 M? 1 pts Submit Answer Tries 0/5 The copper electrode of the above cell is placed in a solution of unknown [Cu2+]. The measured potential at 25°C is 0.136...